Structure 4001328

4001327 << 4001328 >> 4001329
Original COD entry Download CIF Download DOT

Citation: Henderson, Stuart J.; Shebanova, Olga; Hector, Andrew L.; McMillan, Paul F.; Weller, Mark T. (2007). Structural Variations in Pyrochlore-Structured Bi2Hf2O7, Bi2Ti2O7and Bi2Hf2-xTixO7Solid Solutions as a Function of Composition and Temperature by Neutron and X-ray Diffraction and Raman Spectroscopy. Chemistry of Materials, 19, pp. 1712-.

Formula: Bi2 Hf2 O7

Chemical name: ?

Cell parameters:

  • a = 15.3536(4) Å
  • b = 15.3320(4) Å
  • c = 21.82526(31) Å
  • α = 90.0°
  • β = 90.051(5)°
  • γ = 90.0°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Bi64 Hf64 O224 (Bi2 Hf2 O7)

Multiplicity: 1

Coordination sequences:

  • 2, 3, 15, 17, 45, 61, 135, 149, 232, 262
  • 2, 3, 18, 23, 43, 74, 135, 183, 246, 303
  • 2, 4, 9, 28, 32, 78, 101, 194, 211, 307
  • 2, 5, 7, 34, 39, 90, 109, 191, 230, 321
  • 2, 6, 12, 37, 62, 91, 143, 213, 263, 342
  • 2, 6, 13, 27, 44, 71, 134, 164, 259, 289
  • 2, 6, 14, 30, 50, 90, 125, 177, 248, 327
  • 2, 6, 15, 29, 54, 74, 141, 180, 251, 316
  • 2, 6, 15, 35, 53, 93, 161, 196, 258, 325
  • 2, 7, 11, 34, 44, 92, 110, 208, 217, 358
  • 2, 7, 15, 24, 52, 78, 153, 173, 257, 305
  • 2, 7, 18, 34, 58, 87, 170, 192, 247, 317
  • 2, 8, 15, 34, 48, 92, 130, 204, 232, 327
  • 2, 8, 17, 39, 53, 92, 157, 197, 259, 321
  • 2, 8, 23, 44, 63, 108, 166, 200, 266, 369
  • 2, 9, 15, 36, 54, 96, 148, 209, 252, 324
  • 2, 10, 12, 39, 43, 127, 127, 227, 201, 401
  • 2, 10, 12, 41, 49, 128, 120, 228, 225, 396
  • 2, 10, 12, 42, 47, 121, 122, 235, 225, 384
  • 2, 10, 19, 37, 61, 90, 155, 201, 292, 340
  • 2, 11, 13, 38, 54, 134, 126, 225, 224, 390
  • 2, 11, 13, 39, 55, 129, 127, 233, 236, 378
  • 2, 11, 13, 41, 49, 128, 140, 218, 238, 394
  • 2, 11, 14, 42, 49, 121, 126, 241, 227, 374
  • 2, 11, 14, 44, 42, 124, 139, 229, 218, 391
  • 2, 11, 15, 43, 54, 120, 129, 226, 252, 412
  • 2, 11, 15, 44, 56, 130, 139, 222, 221, 413
  • 2, 11, 15, 45, 45, 121, 124, 242, 229, 378
  • 2, 11, 15, 47, 58, 131, 146, 213, 258, 414
  • 2, 11, 16, 45, 54, 117, 129, 242, 235, 379
  • 2, 11, 17, 50, 62, 128, 134, 226, 262, 382
  • 2, 12, 14, 43, 62, 127, 125, 214, 265, 390
  • 2, 12, 15, 40, 55, 123, 138, 225, 254, 382
  • 2, 12, 15, 44, 52, 127, 137, 244, 246, 383
  • 2, 12, 17, 44, 57, 123, 143, 236, 237, 389
  • 2, 13, 16, 39, 55, 119, 144, 233, 259, 389
  • 2, 13, 16, 39, 61, 118, 144, 237, 257, 376
  • 2, 14, 18, 41, 60, 120, 138, 230, 263, 387
  • 2, 14, 18, 42, 55, 121, 139, 229, 248, 391
  • 3, 4, 17, 21, 53, 76, 146, 163, 259, 296
  • 3, 4, 17, 22, 67, 82, 151, 179, 281, 314
  • 3, 5, 21, 24, 63, 84, 152, 163, 276, 302
  • 3, 11, 12, 43, 48, 130, 138, 229, 225, 401
  • 3, 11, 13, 41, 42, 121, 123, 240, 235, 397
  • 3, 11, 14, 44, 54, 125, 126, 257, 241, 401
  • 3, 11, 14, 46, 51, 135, 128, 221, 227, 420
  • 3, 12, 12, 43, 51, 125, 129, 237, 248, 394
  • 3, 12, 13, 41, 51, 136, 138, 213, 233, 393
  • 3, 12, 13, 42, 48, 122, 118, 244, 243, 373
  • 3, 12, 14, 42, 54, 131, 128, 228, 243, 393
  • 3, 12, 14, 43, 56, 129, 123, 233, 240, 395
  • 3, 12, 14, 43, 57, 125, 142, 240, 247, 389
  • 3, 12, 14, 48, 53, 122, 134, 239, 228, 420
  • 3, 12, 15, 40, 48, 125, 134, 231, 243, 401
  • 3, 12, 15, 44, 46, 116, 131, 238, 224, 409
  • 3, 12, 15, 44, 52, 121, 130, 224, 246, 389
  • 3, 12, 15, 46, 56, 123, 127, 231, 258, 376
  • 3, 12, 15, 47, 59, 136, 138, 239, 240, 398
  • 3, 12, 15, 50, 53, 124, 140, 236, 265, 384
  • 3, 12, 15, 54, 60, 134, 136, 236, 259, 416
  • 3, 12, 16, 45, 57, 134, 138, 223, 253, 395
  • 3, 12, 16, 50, 59, 128, 144, 232, 247, 396
  • 3, 12, 17, 50, 63, 123, 143, 239, 271, 388
  • 3, 13, 14, 37, 56, 132, 138, 239, 246, 375
  • 3, 13, 14, 40, 52, 135, 130, 212, 235, 393
  • 3, 13, 14, 42, 55, 133, 140, 226, 260, 383
  • 3, 13, 14, 44, 47, 121, 123, 241, 234, 411
  • 3, 13, 15, 44, 48, 134, 116, 221, 224, 389
  • 3, 13, 15, 44, 57, 124, 123, 240, 245, 393
  • 3, 13, 15, 44, 61, 130, 133, 219, 247, 376
  • 3, 13, 15, 45, 53, 124, 133, 235, 256, 388
  • 3, 13, 15, 46, 65, 116, 138, 225, 280, 370
  • 3, 13, 16, 41, 47, 125, 132, 234, 231, 408
  • 3, 13, 16, 42, 53, 121, 145, 235, 256, 382
  • 3, 13, 16, 47, 60, 134, 138, 227, 253, 397
  • 3, 13, 16, 49, 53, 138, 142, 247, 240, 406
  • 3, 13, 16, 49, 59, 121, 150, 237, 265, 387
  • 3, 13, 16, 56, 70, 135, 144, 241, 290, 397
  • 3, 13, 17, 44, 53, 130, 131, 230, 247, 394
  • 3, 13, 17, 46, 60, 126, 149, 249, 270, 399
  • 3, 13, 17, 47, 58, 134, 140, 221, 257, 391
  • 3, 13, 17, 49, 55, 133, 134, 240, 252, 397
  • 3, 13, 17, 51, 70, 138, 136, 222, 296, 408
  • 3, 13, 17, 52, 59, 135, 138, 245, 285, 405
  • 3, 13, 17, 54, 60, 127, 133, 244, 263, 397
  • 3, 13, 18, 49, 50, 121, 138, 254, 252, 401
  • 3, 13, 20, 47, 71, 130, 140, 218, 295, 383
  • 3, 14, 13, 42, 57, 135, 153, 243, 264, 378
  • 3, 14, 14, 44, 60, 125, 127, 237, 235, 405
  • 3, 14, 15, 39, 59, 139, 138, 225, 246, 396
  • 3, 14, 16, 40, 53, 127, 147, 229, 259, 399
  • 3, 14, 16, 40, 58, 128, 153, 227, 267, 400
  • 3, 14, 16, 43, 58, 130, 137, 226, 248, 405
  • 3, 14, 16, 52, 61, 134, 152, 241, 269, 409
  • 3, 14, 17, 45, 52, 128, 140, 250, 262, 380
  • 3, 14, 17, 48, 60, 120, 157, 239, 271, 410
  • 3, 14, 17, 49, 55, 122, 137, 248, 241, 415
  • 3, 14, 18, 40, 57, 140, 141, 244, 266, 391
  • 3, 14, 18, 44, 61, 125, 150, 245, 284, 395
  • 3, 14, 19, 49, 54, 122, 145, 251, 255, 392
  • 3, 14, 19, 50, 60, 131, 148, 250, 257, 414
  • 3, 14, 19, 55, 64, 122, 157, 231, 274, 397
  • 3, 14, 20, 40, 60, 113, 148, 237, 277, 381
  • 3, 14, 20, 46, 61, 145, 150, 254, 262, 402
  • 3, 14, 20, 48, 57, 135, 143, 233, 252, 400
  • 3, 14, 21, 53, 65, 127, 148, 255, 269, 392
  • 3, 14, 23, 42, 66, 101, 189, 220, 292, 340
  • 3, 15, 19, 40, 65, 123, 151, 219, 289, 382
  • 3, 15, 20, 47, 52, 137, 128, 242, 253, 434
  • 3, 15, 20, 50, 65, 123, 152, 241, 276, 371
  • 3, 15, 21, 45, 75, 133, 165, 214, 283, 367
  • 3, 15, 22, 51, 72, 129, 145, 244, 251, 391
  • 3, 15, 24, 49, 62, 137, 148, 238, 281, 391
  • 3, 16, 16, 46, 63, 126, 148, 230, 254, 419
  • 3, 16, 20, 45, 50, 127, 151, 259, 255, 409
  • 3, 17, 21, 50, 77, 126, 162, 237, 275, 372
  • 4, 5, 22, 27, 75, 79, 162, 165, 290, 308
  • 4, 5, 25, 35, 78, 94, 167, 217, 270, 343
  • 4, 6, 26, 29, 70, 84, 173, 200, 281, 312
  • 4, 7, 20, 35, 71, 113, 164, 211, 276, 354
  • 4, 7, 23, 42, 74, 109, 154, 229, 304, 350
  • 4, 8, 20, 29, 62, 91, 166, 197, 280, 331
  • 4, 8, 20, 35, 62, 121, 146, 200, 273, 377
  • 4, 8, 21, 40, 62, 114, 152, 239, 272, 345
  • 4, 8, 22, 38, 64, 109, 150, 220, 270, 347
  • 4, 9, 22, 35, 72, 109, 169, 199, 277, 367
  • 4, 12, 27, 42, 78, 114, 174, 227, 285, 395
  • 4, 17, 22, 52, 62, 133, 156, 247, 267, 411
  • 5, 9, 24, 34, 73, 95, 160, 214, 282, 357
  • 5, 9, 24, 36, 75, 108, 185, 221, 269, 356
  • 5, 9, 26, 40, 77, 98, 172, 212, 322, 327
  • 5, 10, 25, 37, 74, 110, 174, 203, 288, 371
  • 5, 10, 27, 39, 74, 121, 179, 227, 294, 364
  • 5, 11, 17, 40, 53, 123, 152, 238, 260, 398
  • 5, 12, 21, 44, 67, 143, 154, 225, 254, 399
  • 5, 13, 19, 46, 76, 118, 145, 232, 281, 397
  • 5, 13, 21, 40, 62, 126, 142, 248, 264, 414
  • 6, 8, 28, 34, 99, 101, 198, 174, 351, 322
  • 6, 8, 31, 34, 100, 102, 192, 195, 337, 342
  • 6, 8, 31, 36, 95, 101, 208, 189, 342, 350
  • 6, 9, 31, 32, 95, 102, 202, 187, 348, 335
  • 6, 9, 33, 41, 100, 104, 199, 200, 353, 351
  • 6, 10, 31, 44, 67, 126, 174, 245, 286, 371
  • 6, 10, 35, 35, 93, 100, 203, 190, 358, 335
  • 6, 10, 36, 40, 104, 118, 197, 207, 356, 362
  • 6, 10, 37, 44, 109, 114, 180, 224, 360, 373
  • 6, 11, 24, 47, 73, 123, 176, 243, 293, 392
  • 6, 11, 36, 34, 108, 106, 197, 197, 352, 371
  • 6, 12, 28, 46, 77, 120, 160, 244, 297, 386
  • 6, 13, 25, 42, 76, 121, 169, 244, 298, 385
  • 6, 13, 29, 50, 80, 137, 157, 231, 286, 378
  • 6, 14, 21, 50, 62, 141, 142, 246, 274, 400
  • 6, 14, 27, 41, 71, 129, 149, 227, 282, 385
  • 7, 9, 28, 40, 103, 115, 195, 188, 342, 348
  • 7, 9, 29, 35, 98, 115, 202, 200, 336, 374
  • 7, 9, 32, 31, 93, 103, 207, 194, 350, 346
  • 7, 9, 32, 35, 101, 113, 208, 200, 348, 344
  • 7, 10, 31, 37, 94, 106, 201, 220, 348, 371
  • 7, 10, 32, 41, 87, 111, 211, 216, 345, 372
  • 7, 10, 33, 38, 97, 103, 209, 206, 326, 336
  • 7, 10, 35, 44, 98, 116, 200, 218, 346, 369
  • 7, 11, 32, 39, 100, 115, 211, 212, 334, 363
  • 7, 11, 34, 42, 99, 109, 189, 213, 348, 366
  • 7, 11, 36, 44, 101, 109, 203, 198, 334, 351
  • 7, 12, 34, 43, 96, 112, 203, 211, 342, 351
  • 7, 12, 36, 43, 100, 113, 205, 209, 335, 360
  • 8, 10, 28, 41, 95, 123, 204, 208, 329, 375
  • 8, 10, 31, 48, 97, 107, 190, 231, 331, 373
  • 8, 10, 32, 40, 109, 118, 192, 214, 352, 365
  • 8, 11, 32, 34, 97, 97, 201, 189, 362, 357
  • 8, 11, 32, 39, 100, 104, 194, 198, 347, 345
  • 8, 11, 32, 46, 100, 104, 198, 200, 336, 361
  • 8, 11, 33, 38, 93, 113, 211, 210, 337, 371
  • 8, 12, 33, 37, 91, 116, 201, 201, 360, 358
  • 8, 12, 36, 51, 97, 118, 196, 230, 325, 376
  • 9, 11, 31, 47, 103, 125, 186, 210, 343, 382
span 1 {1 1 1}