Structure 4003954

4003953 << 4003954 >> 4003959
Original COD entry Download CIF Download DOT

Citation: Mark, Justin; Woo, Katherine E.; Zhu, Weidi; Ji, Bingheng; Lee, Shannon J.; Adeyemi, Adedoyin N.; Sen, Sabyasachi; Kovnir, Kirill (2021). Two-Dimensional and Three-Dimensional Tetrel-Arsenide Frameworks Templated by Li and Cs Cations. Chemistry of Materials, 33, pp. 4586-4595.

Formula: As7 Ge4.93 Li1.07

Cell parameters:

  • a = 10.0496(6) Å
  • b = 3.7429(2) Å
  • c = 15.3975(8) Å
  • α = 90°
  • β = 93.929(2)°
  • γ = 90°

List type: noninterleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0.5 0;1;0)

Dimensionality: 2

Formula: As14 Ge10 Li2 (As7 Ge5 Li)

Coordination sequences:

  • 1, 3, 7, 12, 16, 22, 27, 30, 35, 35
  • 3, 7, 9, 15, 18, 28, 31, 38, 33, 47
  • 3, 7, 10, 12, 22, 26, 30, 32, 48, 42
  • 3, 8, 14, 17, 19, 26, 34, 40, 45, 56
  • 3, 9, 10, 18, 24, 24, 28, 34, 44, 44
  • 3, 9, 11, 17, 24, 30, 31, 41, 40, 48
  • 3, 9, 14, 19, 22, 31, 31, 39, 40, 48
  • 3, 9, 15, 21, 24, 26, 33, 37, 42, 46
  • 4, 7, 12, 16, 22, 27, 30, 35, 35, 45
  • 4, 8, 11, 17, 24, 26, 31, 39, 50, 46
  • 4, 8, 13, 17, 22, 29, 39, 32, 39, 49
  • 4, 8, 15, 19, 26, 24, 31, 39, 48, 40
  • 4, 10, 14, 18, 24, 31, 33, 34, 37, 46
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