Structure 4030356

4030355 << 4030356 >> 4030357
Original COD entry Download CIF Download DOT

Citation: Ijjaali, M.; Venturini, G.; Gerardin, R.; Malaman, B.; Gleitzer, C. (1991). Synthesis, structure and physical properties of a mixed-valence iron diphosphate Fe3(P2O7)2 ; first example of trigonal prismatic Fe2+ with O2- ligands. European Journal of Solid State and Inorganic Chemistry, 28, pp. 983-998.

Formula: Fe3 O14 P4

Cell parameters:

  • a = 8.9500(7) Å
  • b = 12.235(2) Å
  • c = 10.174(1) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Fe12 O56 P16 (Fe3 O14 P4)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 7, 34, 40, 82, 60, 130, 140, 242
  • 2, 6, 8, 32, 32, 72, 57, 146, 140, 228
  • 2, 9, 13, 36, 36, 85, 90, 154, 154, 236
  • 2, 9, 13, 36, 36, 86, 91, 148, 152, 232
  • 2, 9, 14, 38, 37, 81, 87, 153, 161, 243
  • 3, 12, 13, 34, 41, 87, 83, 164, 150, 250
  • 3, 12, 14, 36, 40, 88, 89, 164, 153, 245
  • 3, 12, 14, 36, 40, 88, 89, 164, 155, 250
  • 4, 5, 23, 27, 63, 59, 120, 120, 202, 203
  • 4, 6, 25, 27, 58, 56, 122, 128, 207, 183
  • 7, 10, 24, 24, 64, 71, 126, 132, 197, 210
  • 8, 12, 21, 32, 62, 78, 131, 120, 208, 208
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