Structure 4030488

4030487 << 4030488 >> 4030496
Original COD entry Download CIF Download DOT

Citation: Malaman, B.; Ijjaali, M.; Gerardin, R.; Venturini, G.; Gleitzer, C. (1992). Fe7(P2O7)4, a mixed-valence iron diphosphate, the missing link between Fe2P2O7 and Fe3(P2O7)2. European Journal of Solid State and Inorganic Chemistry, 29, pp. 1269-1284.

Formula: Fe7 O28 P8

Cell parameters:

  • a = 8.4327(1) Å
  • b = 9.695(1) Å
  • c = 23.663(4) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Fe28 O112 P32 (Fe7 O28 P8)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 9, 32, 35, 94, 69, 163, 123, 278
  • 2, 6, 10, 38, 36, 87, 69, 166, 119, 271
  • 2, 8, 10, 32, 34, 93, 68, 161, 121, 276
  • 2, 8, 11, 33, 31, 91, 75, 175, 123, 278
  • 2, 8, 12, 36, 34, 93, 70, 159, 117, 275
  • 2, 8, 13, 41, 39, 99, 71, 166, 125, 287
  • 3, 11, 14, 43, 39, 101, 83, 199, 129, 283
  • 3, 11, 15, 44, 39, 105, 84, 192, 127, 286
  • 3, 11, 15, 45, 39, 97, 77, 189, 130, 285
  • 3, 11, 16, 49, 41, 100, 79, 192, 132, 292
  • 3, 12, 15, 42, 38, 99, 75, 174, 128, 293
  • 3, 12, 15, 47, 39, 93, 76, 179, 123, 277
  • 3, 12, 16, 44, 38, 98, 76, 177, 126, 288
  • 3, 12, 17, 48, 42, 106, 79, 185, 133, 306
  • 4, 5, 20, 23, 65, 56, 144, 105, 234, 155
  • 4, 6, 24, 24, 66, 56, 137, 99, 225, 157
  • 4, 6, 26, 27, 68, 54, 133, 99, 229, 158
  • 4, 7, 26, 27, 74, 59, 141, 105, 244, 164
  • 5, 8, 28, 28, 73, 61, 150, 106, 244, 166
  • 6, 8, 24, 22, 68, 62, 148, 100, 230, 160
  • 6, 8, 24, 25, 72, 57, 133, 99, 235, 163
  • 6, 9, 28, 25, 66, 56, 138, 99, 220, 161
  • 6, 9, 28, 29, 78, 60, 140, 103, 240, 167
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