Structure 4060796

4060781 << 4060796 >> 4060955
Original COD entry Download CIF Download DOT

Citation: Lee, Heung-Sae; Bae, Jin-Young; Kim, Dae-Hyun; Kim, Hoon Sik; Kim, Sung-Joon; Cho, Sungil; Ko, Jaejung; Kang, Sang Ook (2002). Rhodium and Iridium Phosphinothiolato Complexes. Synthesis and Crystal Structures of Mononuclear [M(cod)(S,P-SC~2~B~10~H~10~PPh~2~)] and Dinuclear [M~2~(CO)~2~(S,P-\m-SC~2~B~10~H~10~PPh~2~)] (M = Rh, Ir) and Their Performance in Catalytic Carbonylation. Organometallics, 21, pp. 210-219.

Formula: C36 H54 B20 O2 P2 Rh2 S2

Cell parameters:

  • a = 14.633(2) Å
  • b = 30.160(2) Å
  • c = 10.8636(9) Å
  • α = 90.00°
  • β = 92.414(9)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 4, entity 5 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C8 (C)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 5, entity 6 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C8 (C)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}