Structure 4072829

4072766 << 4072829 >> 4073297

Citation: Clark, George R.; Lu, Guo-Liang; Roper, Warren R.; Wright, L. James (2007). Stepwise Reactions of Acetylenes with Iridium Thiocarbonyl Complexes To Produce Isolable Iridacyclobutadienes and Conversion of These to either Cyclopentadienyliridium or Tethered Iridabenzene Complexes. Organometallics, 26, pp. 2167-.

Formula: C59.5 H52.5 Cl Ir O6 P2 S

Chemical name: ?

Cell parameters:

a = 12.0065(4) Å
b = 19.2784(6) Å
c = 22.4702(8) Å

α = 90.00°
β = 100.255(1)°
γ = 90.00°

List type: interleaving

List: 1D

Molecules

CIF datablock 4, entity 5 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C30 (C)

Multiplicity: 1

Coordination sequences:

2, 5, 5, 6, 8, 4, 4, 5, 9, 4
2, 6, 6, 4, 4, 6, 7, 6, 4, 4
3, 4, 5, 7, 6, 5, 4, 7, 5, 6
3, 5, 5, 7, 5, 5, 4, 4, 6, 5
3, 5, 8, 5, 5, 4, 4, 4, 4, 6
3, 6, 5, 5, 4, 5, 9, 4, 4, 4
3, 6, 6, 7, 4, 4, 4, 4, 4, 7
4, 4, 4, 4, 6, 5, 5, 4, 6, 5
4, 4, 5, 4, 5, 6, 4, 4, 7, 4
4, 4, 6, 5, 4, 7, 5, 6, 4, 7
4, 4, 7, 4, 4, 6, 8, 4, 4, 5
4, 5, 5, 4, 6, 5, 5, 6, 5, 4
4, 5, 6, 4, 5, 6, 4, 7, 4, 4
4, 5, 6, 5, 6, 4, 4, 4, 7, 4
5, 4, 4, 4, 5, 6, 4, 4, 7, 4

span 1 {1 1 1}

highlight edges

CIF datablock 5, entity 6 of 2