Structure 4104974

4104959 << 4104974 >> 4104975
Original COD entry Download CIF Download DOT

Citation: Ann M. Chippindale; Simon J. Hibble (2009). Helices, Chirality and Interpenetration: the Versatility and Remarkable Interconversion of Silver-Copper Cyanide Frameworks. Journal of the American Chemical Society, 131, pp. 12736-12744.

Formula: C24 Ag6 Cs9 Cu9 N24

Chemical name: caesium copper(I) silver(I) cyanideCs3Ag2Cu3(CN)8

Cell parameters:

  • a = 29.8146(5) Å
  • b = 29.8146(5) Å
  • c = 6.9588(1) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 1-3D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 5

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C144 Ag24 Cu36 N144 (C12 Ag2 Cu3 N12)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: Cs4 (Cs)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 2, entity 3 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: Cs4 (Cs)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 3, entity 4 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: Cs4 (Cs)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}

CIF datablock 4, entity 5 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: Cs4 (Cs)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 2, 2, 2, 2, 2, 2, 2
span 1 {1 1 1}