Structure 4108256

4108241 << 4108256 >> 4108262
Original COD entry Download CIF Download DOT

Citation: Aaron J. Celestian; James D. Kubicki; Jonathon Hanson; Abraham Clearfield; John B. Parise (2008). The Mechanism Responsible for Extraordinary Cs Ion Selectivity in Crystalline Silicotitanate. Journal of the American Chemical Society, 130, pp. 11689-11694.

Formula: Cs1.44 H6.56 O32 Si4 Ti8

Cell parameters:

  • a = 7.8258(4) Å
  • b = 7.8258(4) Å
  • c = 11.981(1) Å
  • α = 90.000°
  • β = 90.000°
  • γ = 90.000°

List type: interleaving

List: 1-3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O28 Si4 Ti8 (O7 Si Ti2)

Multiplicity: 1

Coordination sequences:

  • 2, 11, 13, 24, 37, 52, 78, 98, 141, 153
  • 2, 16, 23, 16, 36, 66, 92, 106, 134, 151
  • 3, 13, 10, 26, 29, 58, 70, 108, 106, 154
  • 4, 4, 20, 20, 42, 54, 68, 118, 138, 158
  • 9, 13, 16, 29, 42, 66, 86, 111, 129, 183
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CIF datablock 1, entity 2 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: Cs6 (Cs)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 4, 2, 4, 2, 4, 2, 4, 2
  • 3, 3, 3, 3, 3, 3, 3, 3, 3, 3
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