Structure 4114009

4114001 << 4114009 >> 4114010
Original COD entry Download CIF Download DOT

Citation: J.-H. Liao; G. M. Marking; K. F. Hsu; Y. Matsushita; M. D. Ewbank; R. Borwick; P. Cunningham; M. J. Rosker; M. G. Kanatzidis (2003). \a- and \b-A2Hg3M2S8 (A = K, Rb; M = Ge, Sn): Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response. Journal of the American Chemical Society, 125, pp. 9484-9493.

Formula: Ge2 Hg3 K2 S8

Chemical name: potassium mercury germanium sulfide (2/3/2/8)

Cell parameters:

  • a = 19.082(8) Å
  • b = 9.551(4) Å
  • c = 8.2871(8) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ge8 Hg12 S32 (Ge2 Hg3 S8)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 6, 8, 22, 24, 58, 48, 82, 66
  • 2, 4, 5, 14, 16, 40, 38, 70, 56, 112
  • 2, 6, 8, 19, 18, 36, 34, 72, 60, 114
  • 3, 9, 10, 22, 21, 43, 37, 74, 67, 135
  • 4, 5, 12, 13, 32, 30, 56, 46, 98, 84
  • 4, 6, 16, 16, 30, 26, 58, 54, 104, 78
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