Structure 4124847

4124846 << 4124847 >> 4124848
Original COD entry Download CIF Download DOT

Citation: Liao, J.-H.; Marking, G.M.; Ewbank, M.D.; Hsu, K.-F.; Rosker, M.J.; Kanatzidis, M.G.; Matsushita, Y.; Borwick, R.; Cunningham, P. (2003). Alpha- and beta-(A2 Hg3 M2 S8) (A = K, Rb; M = Ge, Sn): polar quaternary chalcogenides with strong nonlinear optical response. Journal of the American Chemical Society, 125, pp. 9484-9493.

Formula: Ge2 Hg3 K1.6 Rb0.4 S8

Chemical name: (K1.6 Rb0.4) (Hg3 Ge2 S8)

Cell parameters:

  • a = 9.649 Å
  • b = 8.393 Å
  • c = 9.72 Å
  • α = 90°
  • β = 95.08°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ge4 Hg6 S16 (Ge2 Hg3 S8)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 6, 8, 22, 24, 58, 48, 82, 66
  • 2, 4, 5, 14, 16, 40, 38, 70, 56, 112
  • 2, 6, 8, 19, 18, 36, 34, 72, 60, 114
  • 3, 9, 10, 22, 21, 43, 37, 74, 67, 135
  • 4, 5, 12, 13, 32, 30, 56, 46, 98, 84
  • 4, 6, 16, 16, 30, 26, 58, 54, 104, 78
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