Structure 4125035

4125034 << 4125035 >> 4125036
Original COD entry Download CIF Download DOT

Citation: Hill, Joshua A.; Thompson, Amber L.; Goodwin, Andrew L. (2016). Dicyanometallates as Model Extended Frameworks.. Journal of the American Chemical Society, 138, pp. 5886-5896.

Formula: C50 H42 Au5 Cu2 N11 O2 P2

Chemical name: bis(triphenylphosphoranylidene)ammonium copper dicyanoaurate ethanolate

Cell parameters:

  • a = 27.9505(6) Å
  • b = 15.0898(4) Å
  • c = 13.4803(3) Å
  • α = 90°
  • β = 96.629(2)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 4, entity 5 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C40 Au20 Cu8 N40 (C10 Au5 Cu2 N10)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 8, 8, 8, 16, 24, 24, 40
  • 2, 2, 5, 5, 8, 12, 16, 20, 32, 40
  • 2, 3, 7, 7, 10, 19, 20, 19, 32, 36
  • 2, 5, 5, 5, 9, 16, 16, 24, 36, 40
  • 2, 5, 6, 7, 10, 16, 20, 28, 33, 34
  • 3, 4, 4, 10, 16, 16, 18, 22, 24, 40
  • 5, 5, 5, 9, 13, 13, 24, 32, 32, 40
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