Structure 4301932

4301916 << 4301932 >> 4301939
Original COD entry Download CIF Download DOT

Citation: N. Barrier; B. Fontaine; S. Pierrefixe; R. Gautier; P. Gougeon (2009). Synthesis, Crystal and Electronic Structures, and Physical Properties of the Novel Compounds LaR4Mo36O52 (R = Dy, Er, Yb, and Y) Containing Infinite Chains of Trans-Edge-Shared Mo6 Octahedra and Mo2 Pairs and Rectangular Mo4 Clusters with Triple Mo-Mo Bonds. Inorganic Chemistry, 48, pp. 3848-3856.

Formula: Er4 La Mo36 O52

Chemical name: ?

Cell parameters:

  • a = 19.8348(2) Å
  • b = 19.8348(2) Å
  • c = 5.65940(10) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Er8 La2 Mo80 O104 (Er4 La Mo40 O52)

Multiplicity: 1

Coordination sequences:

  • 3, 29, 75, 137, 243, 352, 496, 692, 845, 1068
  • 4, 26, 66, 148, 209, 332, 496, 627, 822, 1058
  • 4, 29, 65, 135, 247, 340, 495, 650, 870, 1067
  • 4, 29, 73, 142, 236, 359, 505, 653, 839, 1066
  • 4, 30, 69, 130, 242, 348, 456, 639, 893, 1061
  • 4, 30, 70, 142, 232, 347, 478, 661, 846, 1061
  • 4, 30, 71, 149, 233, 359, 514, 699, 867, 1062
  • 5, 31, 57, 112, 217, 300, 436, 594, 772, 996
  • 5, 31, 60, 111, 206, 304, 409, 587, 766, 1007
  • 12, 33, 91, 159, 252, 402, 508, 711, 889, 1135
  • 12, 36, 104, 162, 276, 442, 572, 810, 904, 1186
  • 12, 38, 79, 158, 279, 369, 539, 717, 904, 1142
  • 12, 38, 88, 180, 256, 388, 562, 694, 918, 1182
  • 12, 39, 86, 166, 269, 386, 521, 721, 926, 1158
  • 12, 39, 92, 166, 240, 384, 537, 659, 908, 1155
  • 12, 42, 85, 169, 268, 398, 569, 733, 927, 1151
  • 12, 42, 89, 152, 258, 359, 517, 693, 882, 1107
  • 13, 26, 55, 137, 214, 295, 433, 614, 804, 989
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