Structure 4302828

4302823 << 4302828 >> 4302866
Original COD entry Download CIF Download DOT

Citation: Wen-Guan Lu; Long Jiang; Xiao-Long Feng; Tong-Bu Lu (2009). Three-Dimensional Lanthanide Anionic Metal-Organic Frameworks with Tunable Luminescent Properties Induced by Cation Exchange. Inorganic Chemistry, 48, pp. 6997-6999.

Formula: C28 H44 K5 N8 O52 Tb5

Chemical name: ?

Cell parameters:

  • a = 18.2052(12) Å
  • b = 18.2052(12) Å
  • c = 10.0224(13) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 1-3D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 5

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C96 H16 N32 O96 Tb10 (C48 H8 N16 O48 Tb5)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: K2 O6 (K O3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 2, 4, 2, 2, 4, 2, 2
  • 2, 3, 3, 2, 3, 3, 2, 3, 3, 2
  • 3, 2, 2, 4, 2, 2, 4, 2, 2, 4
span 1 {1 1 1}

CIF datablock 2, entity 3 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: K2 O6 (K O3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 2, 4, 2, 2, 4, 2, 2
  • 2, 3, 3, 2, 3, 3, 2, 3, 3, 2
  • 3, 2, 2, 4, 2, 2, 4, 2, 2, 4
span 1 {1 1 1}

CIF datablock 3, entity 4 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: K2 O6 (K O3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 2, 4, 2, 2, 4, 2, 2
  • 2, 3, 3, 2, 3, 3, 2, 3, 3, 2
  • 3, 2, 2, 4, 2, 2, 4, 2, 2, 4
span 1 {1 1 1}

CIF datablock 4, entity 5 of 5

Basis: (0;0;1)

Dimensionality: 1

Formula: K2 O6 (K O3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 2, 4, 2, 2, 4, 2, 2
  • 2, 3, 3, 2, 3, 3, 2, 3, 3, 2
  • 3, 2, 2, 4, 2, 2, 4, 2, 2, 4
span 1 {1 1 1}