Structure 4305345

4305342 << 4305345 >> 4305346
Original COD entry Download CIF Download DOT

Citation: Efrain E. Rodriguez; Fr\'ed\'eric Poineau; Anna Llobet; Ken Czerwinski; Ram Seshadri; Anthony K. Cheetham (2008). Preparation and Crystal Structures of Bismuth Technetates: A New Metal Oxide System. Inorganic Chemistry, 47, pp. 6281-6288.

Formula: Bi2 O6.86 Tc2

Chemical name: Bismuth technetium oxide (2/2/6.86)

Cell parameters:

  • a = 10.47458(10) Å
  • b = 10.47458 Å
  • c = 10.47458 Å
  • α = 90.0°
  • β = 90.0°
  • γ = 90.0°

List type: interleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O48 Tc16 (O3 Tc)

Multiplicity: 1

Coordination sequences:

  • 2, 10, 8, 31, 24, 94, 56, 193, 92, 322
  • 6, 6, 24, 18, 72, 48, 168, 78, 276, 126
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CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Bi16 O8 (Bi2 O)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 18, 18, 48, 30, 78, 54, 126
  • 4, 4, 12, 12, 36, 24, 60, 42, 108, 64
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