Structure 4306980

4306979 << 4306980 >> 4306984
Original COD entry Download CIF Download DOT

Citation: Jorge A. R. Navarro; Elisa Barea; Juan M. Salas; Norberto Masciocchi; Simona Galli; Angelo Sironi (2007). Structural and Magnetic Properties of Layered Copper(II) Coordination Polymers Intercalating s and f Metal Ions. Inorganic Chemistry, 46, pp. 2988-2997.

Formula: C8.5 H8 Cu N4.5 O4 Tl0.5

Chemical name: catena-tetrakis(N,N'-pyrimidin-2-olate)-biscopper(ii)-tallium nitrate--methanol solvate

Cell parameters:

  • a = 19.044(2) Å
  • b = 11.0370(10) Å
  • c = 11.451(3) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: C32 H24 Cu4 N16 O8 (C8 H6 Cu N4 O2)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 7, 12, 24, 18, 24, 34
  • 1, 2, 4, 6, 7, 15, 15, 24, 27, 46
  • 1, 2, 4, 9, 13, 24, 18, 24, 34, 64
  • 3, 4, 3, 7, 12, 24, 18, 24, 34, 64
  • 3, 4, 6, 7, 15, 15, 24, 27, 46, 37
  • 3, 4, 9, 13, 24, 18, 24, 34, 64, 40
  • 3, 7, 9, 16, 15, 24, 27, 46, 37, 50
  • 4, 8, 16, 12, 16, 24, 48, 32, 32, 40
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CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: C32 H24 Cu4 N16 O8 (C8 H6 Cu N4 O2)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 7, 12, 24, 18, 24, 34
  • 1, 2, 4, 6, 7, 15, 15, 24, 27, 46
  • 1, 2, 4, 9, 13, 24, 18, 24, 34, 64
  • 3, 4, 3, 7, 12, 24, 18, 24, 34, 64
  • 3, 4, 6, 7, 15, 15, 24, 27, 46, 37
  • 3, 4, 9, 13, 24, 18, 24, 34, 64, 40
  • 3, 7, 9, 16, 15, 24, 27, 46, 37, 50
  • 4, 8, 16, 12, 16, 24, 48, 32, 32, 40
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