Structure 4309517

4309516 << 4309517 >> 4309520
Original COD entry Download CIF Download DOT

Citation: Hugh D. Selby; Benny C. Chan; Ryan F. Hess; Kent D. Abney; Peter K. Dorhout (2005). Three New Phases in the K/Cu/Th /S System: KCuThS~3~, K~2~Cu~2~ThS~4~, and K~3~Cu~3~Th~2~S~7~. Inorganic Chemistry, 44, pp. 6463-6469.

Formula: Cu3 K3 S7 Th2

Chemical name: tripotassium tricopper dithorium heptasulfide

Cell parameters:

  • a = 4.051(2) Å
  • b = 14.023(8) Å
  • c = 24.633(13) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: Cu6 S14 Th4 (Cu3 S7 Th2)

Multiplicity: 1

Coordination sequences:

  • 3, 17, 22, 41, 40, 56, 66, 66, 95, 84
  • 3, 17, 25, 34, 44, 56, 66, 74, 78, 93
  • 4, 18, 29, 38, 49, 52, 67, 78, 87, 98
  • 4, 20, 28, 32, 54, 52, 74, 72, 76, 108
  • 8, 19, 28, 39, 48, 52, 68, 77, 88, 97
  • 8, 22, 24, 36, 52, 52, 76, 68, 80, 106
  • 10, 16, 30, 37, 44, 64, 60, 79, 86, 88
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: Cu6 S14 Th4 (Cu3 S7 Th2)

Multiplicity: 1

Coordination sequences:

  • 3, 17, 22, 41, 40, 56, 66, 66, 95, 84
  • 3, 17, 25, 34, 44, 56, 66, 74, 78, 93
  • 4, 18, 29, 38, 49, 52, 67, 78, 87, 98
  • 4, 20, 28, 32, 54, 52, 74, 72, 76, 108
  • 8, 19, 28, 39, 48, 52, 68, 77, 88, 97
  • 8, 22, 24, 36, 52, 52, 76, 68, 80, 106
  • 10, 16, 30, 37, 44, 64, 60, 79, 86, 88
span 1 {1 1 1}