Structure 4310174

4310163 << 4310174 >> 4310186
Original COD entry Download CIF Download DOT

Citation: Ya Cai; Yan Wang; Yizhi Li; Xiaoshu Wang; Xinquan Xin; Caiming Liu; Hegen Zheng (2005). New Skeletal 3D Polymeric Inorganic Cluster [W4S16Cu16Cl16]n with Cu in Mixed-Valence States: Solid-State Synthesis, Crystal Structure, and Third-Order Nonlinear Optical Properties. Inorganic Chemistry, 44, pp. 9128-9130.

Formula: Cl4 Cu4 S4 W

Chemical name: ?

Cell parameters:

  • a = 11.5262(17) Å
  • b = 11.5262(17) Å
  • c = 5.5308(15) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Cl16 Cu16 S16 W4 (Cl4 Cu4 S4 W)

Multiplicity: 1

Coordination sequences:

  • 4, 21, 36, 95, 114, 224, 292, 418, 492, 636
  • 5, 25, 39, 82, 131, 238, 277, 392, 483, 644
  • 6, 13, 54, 78, 148, 195, 302, 418, 515, 608
  • 9, 17, 48, 69, 150, 202, 337, 362, 489, 653
  • 10, 22, 50, 62, 142, 218, 322, 334, 462, 614
  • 14, 34, 50, 106, 174, 254, 294, 390, 550, 674
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