Structure 4312740

4312736 << 4312740 >> 4312741
Original COD entry Download CIF Download DOT

Citation: St\'ephane Cordier; Fakhili Gulo; Thierry Roisnel; R\'egis Gautier; Boris le Guennic; Jean Fran\,cois Halet; Christiane Perrin (2003). A Novel Layered Niobium Oxychloride Compound Based on Nb2 Pairs and Nb6 Octahedral Clusters: Synthesis and Crystal and Electronic Structures of Nb10Cl16O7. Inorganic Chemistry, 42, pp. 8320-8327.

Formula: Cl16 Nb10 O7

Cell parameters:

  • a = 17.646(5) Å
  • b = 3.264(5) Å
  • c = 12.893(5) Å
  • α = 90°
  • β = 121.243(5)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Cl8 Nb8 O4 (Cl2 Nb2 O)

Multiplicity: 1

Coordination sequences:

  • 2, 19, 45, 52, 58, 88, 112, 148, 144, 148
  • 3, 25, 44, 51, 67, 92, 121, 138, 141, 147
  • 4, 16, 33, 60, 74, 94, 99, 122, 137, 176
  • 4, 22, 48, 78, 86, 96, 102, 136, 160, 198
  • 5, 22, 39, 56, 74, 93, 110, 126, 147, 164
  • 5, 28, 43, 56, 71, 99, 115, 137, 140, 160
  • 6, 30, 44, 50, 72, 96, 128, 132, 140, 146
  • 11, 23, 46, 64, 85, 92, 112, 127, 162, 172
  • 13, 36, 48, 54, 80, 104, 138, 138, 144, 150
  • 14, 36, 45, 62, 77, 108, 122, 144, 145, 166
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CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Cl8 Nb8 O4 (Cl2 Nb2 O)

Multiplicity: 1

Coordination sequences:

  • 2, 19, 45, 52, 58, 88, 112, 148, 144, 148
  • 3, 25, 44, 51, 67, 92, 121, 138, 141, 147
  • 4, 16, 33, 60, 74, 94, 99, 122, 137, 176
  • 4, 22, 48, 78, 86, 96, 102, 136, 160, 198
  • 5, 22, 39, 56, 74, 93, 110, 126, 147, 164
  • 5, 28, 43, 56, 71, 99, 115, 137, 140, 160
  • 6, 30, 44, 50, 72, 96, 128, 132, 140, 146
  • 11, 23, 46, 64, 85, 92, 112, 127, 162, 172
  • 13, 36, 48, 54, 80, 104, 138, 138, 144, 150
  • 14, 36, 45, 62, 77, 108, 122, 144, 145, 166
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