Structure 4318001

4317984 << 4318001 >> 4318002
Original COD entry Download CIF Download DOT

Citation: P. Gall; N. Barrier; R. Gautier; P. Gougeon (2002). Synthesis, Structural Trends, and Physical and Electronic Properties of the Reduced Molybdenum Oxides R4Mo4O11 (R = Nd-Tm and Y) Containing Infinite Chains of Trans-Edge-Shared Octahedral Clusters. Inorganic Chemistry, 41, pp. 2879-2885.

Formula: Mo4 O11 Sm4

Chemical name: ?

Cell parameters:

  • a = 10.8700(7) Å
  • b = 16.0957(14) Å
  • c = 5.7178(2) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Mo16 O44 Sm16 (Mo4 O11 Sm4)

Multiplicity: 1

Coordination sequences:

  • 4, 31, 87, 179, 339, 513, 790, 1100, 1436, 1881
  • 4, 31, 95, 189, 357, 552, 827, 1126, 1554, 1906
  • 4, 33, 96, 215, 364, 561, 831, 1162, 1495, 1979
  • 4, 34, 106, 216, 377, 606, 850, 1187, 1599, 1976
  • 4, 35, 104, 212, 375, 584, 876, 1189, 1570, 1988
  • 4, 37, 103, 223, 374, 606, 863, 1224, 1568, 2025
  • 4, 40, 122, 238, 424, 670, 930, 1278, 1658, 2072
  • 5, 39, 112, 227, 399, 597, 884, 1195, 1589, 2004
  • 12, 44, 115, 243, 404, 615, 901, 1219, 1635, 2050
  • 13, 48, 140, 265, 452, 679, 1004, 1311, 1736, 2178
  • 13, 51, 130, 252, 428, 655, 948, 1283, 1694, 2101
  • 13, 53, 134, 268, 436, 687, 953, 1341, 1707, 2151
  • 14, 60, 153, 282, 491, 722, 1023, 1382, 1789, 2201
  • 16, 63, 146, 286, 452, 716, 1017, 1353, 1740, 2208
  • 16, 69, 155, 298, 489, 747, 1027, 1413, 1790, 2262
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