Structure 4318934

4318868 << 4318934 >> 4318935
Original COD entry Download CIF Download DOT

Citation: Haruo Naruke; Toshihiro Yamase (2002). Structures of Novel R~2~Mo~5~O~18~ and R~6~Mo~12~O~45~ (R= Eu and Gd) Prepared by Thermal Decomposition of Polyoxomolybdate Precursor [R~2~(H~2~O)~12~Mo~8~O~27~].nH~2~O. Inorganic Chemistry, 41, pp. 6514-6520.

Formula: Gd6 Mo12 O45

Cell parameters:

  • a = 9.3409(3) Å
  • b = 10.8826(5) Å
  • c = 11.4377(5) Å
  • α = 104.170(1)°
  • β = 109.288(4)°
  • γ = 109.266(2)°

List type: noninterleaving

List: 3D

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Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Gd6 Mo12 O45 (Gd2 Mo4 O15)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 56, 53, 108, 142, 200, 247, 330
  • 2, 8, 9, 57, 57, 109, 138, 190, 250, 312
  • 2, 10, 10, 50, 54, 118, 140, 198, 252, 330
  • 2, 10, 14, 46, 63, 111, 133, 199, 249, 321
  • 2, 11, 15, 51, 57, 112, 148, 186, 276, 298
  • 2, 11, 15, 51, 59, 113, 145, 182, 274, 309
  • 2, 12, 18, 44, 53, 117, 129, 213, 242, 342
  • 2, 12, 18, 44, 60, 115, 136, 212, 260, 330
  • 2, 12, 18, 51, 72, 118, 148, 210, 276, 320
  • 2, 12, 18, 52, 73, 108, 158, 190, 300, 312
  • 2, 12, 18, 54, 69, 109, 156, 191, 282, 332
  • 2, 12, 21, 49, 64, 103, 165, 195, 281, 300
  • 2, 13, 21, 46, 56, 118, 143, 209, 259, 321
  • 2, 13, 23, 46, 72, 114, 154, 208, 268, 336
  • 2, 13, 24, 50, 75, 100, 162, 192, 310, 317
  • 2, 14, 18, 42, 62, 119, 135, 206, 265, 335
  • 2, 14, 19, 46, 60, 114, 153, 187, 281, 324
  • 3, 14, 14, 55, 50, 126, 142, 217, 265, 315
  • 3, 14, 14, 57, 61, 118, 156, 209, 283, 290
  • 3, 15, 22, 57, 70, 126, 161, 207, 287, 347
  • 3, 16, 16, 54, 58, 128, 124, 216, 272, 315
  • 3, 16, 17, 57, 59, 126, 139, 220, 275, 316
  • 3, 17, 19, 56, 67, 123, 137, 194, 301, 309
  • 4, 5, 34, 33, 79, 98, 169, 208, 276, 331
  • 4, 5, 35, 36, 87, 105, 147, 210, 261, 369
  • 4, 5, 38, 44, 80, 120, 163, 219, 254, 397
  • 5, 11, 37, 50, 68, 130, 162, 236, 257, 385
  • 6, 6, 32, 34, 90, 107, 161, 208, 271, 344
  • 6, 11, 33, 48, 84, 117, 168, 206, 293, 361
  • 9, 12, 31, 39, 87, 110, 168, 232, 257, 359
  • 10, 15, 30, 48, 94, 110, 182, 217, 303, 328
  • 10, 15, 31, 51, 93, 119, 152, 253, 278, 369
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