Structure 4318936

4318935 << 4318936 >> 4318937
Original COD entry Download CIF Download DOT

Citation: Haruo Naruke; Toshihiro Yamase (2002). Structures of Novel R~2~Mo~5~O~18~ and R~6~Mo~12~O~45~ (R= Eu and Gd) Prepared by Thermal Decomposition of Polyoxomolybdate Precursor [R~2~(H~2~O)~12~Mo~8~O~27~].nH~2~O. Inorganic Chemistry, 41, pp. 6514-6520.

Formula: Gd2 Mo5 O18

Cell parameters:

  • a = 19.246(1) Å
  • b = 9.4414(5) Å
  • c = 9.3446(4) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Gd8 Mo20 O72 (Gd2 Mo5 O18)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 42, 32, 80, 44, 200, 116, 276
  • 2, 10, 10, 35, 27, 100, 63, 189, 93, 295
  • 2, 10, 10, 36, 26, 99, 62, 186, 96, 305
  • 2, 10, 10, 37, 26, 96, 63, 187, 96, 305
  • 2, 10, 10, 37, 27, 98, 61, 188, 91, 290
  • 2, 10, 10, 37, 27, 102, 61, 179, 94, 300
  • 2, 10, 10, 38, 27, 98, 59, 178, 96, 310
  • 2, 10, 10, 38, 27, 98, 62, 198, 105, 313
  • 2, 10, 10, 40, 27, 94, 63, 205, 103, 305
  • 4, 4, 24, 21, 64, 42, 157, 89, 247, 117
  • 4, 4, 24, 23, 70, 38, 147, 88, 246, 119
  • 4, 4, 28, 22, 56, 36, 164, 102, 266, 108
  • 8, 8, 24, 18, 84, 56, 152, 74, 264, 146
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