Structure 4320186

4320185 << 4320186 >> 4320200
Original COD entry Download CIF Download DOT

Citation: Ulrich Kortz; Noha K. Al-Kassem; Masha G. Savelieff; Nisrine A. Al Kadi; Masahiro Sadakane (2001). Synthesis and Characterization of Copper-, Zinc-, Manganese-, and Cobalt-Substituted Dimeric Heteropolyanions, [(\a-XW~9~O~33~)~2~M~3~(H~2~O)~3~]^n-^ (n = 12, X = As^III^, Sb^III^, M = Cu^2+^, Zn^2+^; n = 10, X = Se^IV^, Te^IV^, M = Cu^2+^) and [(\a-AsW~9~O~33~)~2~WO(H~2~O)M~2~(H~2~O)~2~]^10-^ (M = Zn^2+^, Mn^2+^, Co^2+^). Inorganic Chemistry, 40, pp. 4742-4749.

Formula: Cu3 K9 Na O85 Te2 W18

Chemical name: ?

Cell parameters:

  • a = 16.6529(9) Å
  • b = 16.6529(9) Å
  • c = 14.0180(11) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu6 O134 Te4 W36 (Cu3 O67 Te2 W18)

Multiplicity: 1

Coordination sequences:

  • 1, 4, 4, 15, 8, 23, 10, 41, 21, 58
  • 1, 4, 4, 18, 10, 28, 8, 18, 4, 16
  • 1, 5, 5, 16, 8, 26, 9, 26, 11, 40
  • 1, 5, 5, 16, 9, 30, 12, 37, 15, 48
  • 1, 5, 5, 16, 10, 34, 16, 55, 24, 69
  • 2, 8, 5, 18, 7, 19, 12, 47, 22, 64
  • 2, 8, 6, 22, 10, 33, 18, 57, 22, 62
  • 2, 8, 8, 33, 17, 47, 17, 53, 23, 81
  • 2, 9, 6, 18, 7, 24, 12, 40, 17, 50
  • 2, 9, 6, 18, 8, 28, 15, 51, 21, 58
  • 2, 9, 6, 19, 9, 30, 12, 33, 13, 45
  • 2, 9, 6, 19, 11, 38, 19, 62, 25, 70
  • 2, 9, 6, 21, 11, 30, 6, 16, 10, 41
  • 2, 9, 7, 22, 11, 42, 22, 65, 24, 67
  • 2, 9, 7, 25, 15, 45, 13, 35, 16, 67
  • 2, 9, 7, 25, 16, 49, 17, 53, 25, 88
  • 2, 10, 6, 17, 7, 23, 10, 29, 13, 49
  • 2, 10, 6, 17, 9, 31, 16, 54, 23, 67
  • 3, 6, 24, 6, 15, 9, 33, 16, 54, 25
  • 3, 11, 7, 24, 8, 26, 12, 34, 16, 56
  • 3, 11, 7, 24, 10, 34, 18, 59, 25, 70
  • 5, 4, 15, 8, 23, 10, 41, 21, 58, 22
  • 5, 4, 18, 10, 28, 8, 18, 4, 16, 16
  • 5, 5, 19, 11, 37, 17, 55, 24, 67, 24
  • 5, 5, 22, 14, 43, 17, 45, 16, 67, 38
  • 6, 5, 16, 8, 26, 9, 26, 11, 40, 22
  • 6, 5, 16, 9, 30, 12, 37, 15, 48, 25
  • 6, 5, 16, 10, 34, 16, 55, 24, 69, 28
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