Structure 4321191

4321190 << 4321191 >> 4321192
Original COD entry Download CIF Download DOT

Citation: Alfredo Burini; Rita Bravi; John P. Fackler,; Rossana Galassi; Tiffany A. Grant; Mohammad A. Omary; Bianca R. Pietroni; Richard J. Staples (2000). Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching TlI and AgI. Structures of {Ag([Au(\m-C2,N3-bzim)]3)2}BF4.CH2Cl2, {Tl([Au(\m-C2,N3-bzim)]3)2}PF6.0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(\m-C(OEt)NC6H4CH3)]3)2}PF6.THF, with MAu6 (M = Ag+, Tl+) Cluster Cores. Inorganic Chemistry, 39, pp. 3158-3165.

Formula: C64 H80 Ag Au6 F6 N6 O7 P

Chemical name: ?

Cell parameters:

  • a = 16.4136(3) Å
  • b = 27.6277(4) Å
  • c = 16.71820(10) Å
  • α = 90.00°
  • β = 105.6440(10)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C118 H138 Ag2 Au12 N12 O12 (C59 H69 Ag Au6 N6 O6)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C118 H138 Ag2 Au12 N12 O12 (C59 H69 Ag Au6 N6 O6)

Multiplicity: 1

span 1 {1 1 1}