Structure 4322279

4322278 << 4322279 >> 4322280
Original COD entry Download CIF Download DOT

Citation: Soazig Picard; Patrick Gougeon; Michel Potel (1999). Synthesis, Structural Evolution, and Theoretical and Physical Studies of the Novel Compounds M2Mo9S11 (M = K, Rb) and Related Metastable Materials CuxK1.8Mo9S11 (x = 0 or 2) Containing Bioctahedral Mo9 Clusters. Inorganic Chemistry, 38, pp. 4422-4429.

Formula: Cu2 K1.8 Mo9 S11

Cell parameters:

  • a = 9.4215(4) Å
  • b = 9.4215(4) Å
  • c = 35.444(2) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

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Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Cu72 K42 Mo54 S66 (Cu12 K7 Mo9 S11)

Multiplicity: 1

Coordination sequences:

  • 6, 24, 62, 120, 228, 314, 468, 656, 786, 1038
  • 6, 33, 82, 145, 258, 392, 519, 663, 869, 1143
  • 7, 30, 74, 139, 233, 350, 498, 647, 851, 1067
  • 8, 38, 80, 150, 246, 382, 498, 686, 868, 1100
  • 10, 37, 82, 155, 265, 375, 513, 693, 896, 1107
  • 11, 30, 76, 159, 227, 364, 503, 664, 854, 1090
  • 11, 32, 82, 155, 236, 368, 523, 651, 892, 1083
  • 12, 38, 93, 164, 251, 388, 539, 681, 909, 1117
  • 14, 44, 90, 166, 282, 392, 510, 726, 920, 1094
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