Structure 4324653

4324652 << 4324653 >> 4324656
Original COD entry Download CIF Download DOT

Citation: Qingxin Chu; Xiaofeng Wang; Xinhao Zhang; Qiliang Li; Xiaoyang Liu (2011). Buckled Layers in K0.66Mn2O4.0.28H2O and K0.99Mn3O6.1.25H2O Synthesized at High Pressure: Implication for the Mechanism of Layer-to-Tunnel Transformation in Manganese Oxides. Inorganic Chemistry, 50, pp. 2049-2051.

Formula: K1.03 Mn2 O4

Chemical name: ?

Cell parameters:

  • a = 12.7592(6) Å
  • b = 2.83850(10) Å
  • c = 10.4665(5) Å
  • α = 90.00°
  • β = 94.797(3)°
  • γ = 90.00°

List type: interleaving

List: 1-2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 6

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Mn4 O8 (Mn O2)

Multiplicity: 1

Coordination sequences:

  • 3, 21, 39, 57, 75, 93, 111, 129, 147, 165
  • 12, 30, 48, 66, 84, 102, 120, 138, 156, 174
span 1 {1 1 1}

CIF datablock 1, entity 2 of 6

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Mn4 O8 (Mn O2)

Multiplicity: 1

Coordination sequences:

  • 3, 21, 39, 57, 75, 93, 111, 129, 147, 165
  • 12, 30, 48, 66, 84, 102, 120, 138, 156, 174
span 1 {1 1 1}

CIF datablock 2, entity 3 of 6

Basis: (0;1;0)

Dimensionality: 1

Formula: K4 (K)

Multiplicity: 1

Coordination sequences:

  • 4, 6, 9, 8, 8, 8, 8, 8, 8, 8
  • 5, 8, 8, 8, 8, 8, 8, 8, 8, 8
span 1 {1 1 1}

CIF datablock 3, entity 4 of 6

Basis: (0;1;0)

Dimensionality: 1

Formula: K4 (K)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 4, entity 5 of 6

Basis: (0;1;0)

Dimensionality: 1

Formula: K2 (K)

Multiplicity: 1

Coordination sequences:

  • 4, 4, 4, 4, 4, 4, 4, 4, 4, 4
span 1 {1 1 1}

CIF datablock 5, entity 6 of 6

Basis: (0;1;0)

Dimensionality: 1

Formula: K2 (K)

Multiplicity: 1

Coordination sequences:

  • 4, 4, 4, 4, 4, 4, 4, 4, 4, 4
span 1 {1 1 1}