Structure 4324753

4324752 << 4324753 >> 4324754
Original COD entry Download CIF Download DOT

Citation: Takeshi Matsumoto; Ho-Chol Chang; Atsushi Kobayashi; Kohei Uosaki; Masako Kato (2011). Metal-Dependent and Redox-Selective Coordination Behaviors of Metalloligand [MoV(1,2-benzenedithiolato)3]-with CuI/AgI Ions. Inorganic Chemistry, 50, pp. 2859-2869.

Formula: C40 H34 Cu2 Mo2 O S12

Cell parameters:

  • a = 19.839(3) Å
  • b = 20.128(3) Å
  • c = 22.311(3) Å
  • α = 90.0000°
  • β = 90.0000°
  • γ = 90.0000°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C72 H48 Cu4 Mo4 S24 (C18 H12 Cu Mo S6)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C72 H48 Cu4 Mo4 S24 (C18 H12 Cu Mo S6)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 2, entity 3 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C72 H48 Cu4 Mo4 S24 (C18 H12 Cu Mo S6)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 2, 6, 10, 18, 26, 34
  • 1, 2, 4, 3, 3, 8, 14, 20, 32, 38
  • 1, 2, 4, 4, 7, 10, 18, 26, 34, 38
  • 1, 2, 4, 5, 9, 14, 20, 32, 38, 38
  • 2, 9, 13, 21, 27, 34, 38, 38, 38, 38
  • 3, 4, 3, 2, 6, 10, 18, 26, 34, 38
  • 3, 4, 3, 3, 8, 14, 20, 32, 38, 38
  • 3, 4, 4, 7, 10, 18, 26, 34, 38, 38
  • 3, 4, 5, 9, 14, 20, 32, 38, 38, 38
  • 3, 5, 9, 11, 18, 26, 34, 38, 38, 38
  • 3, 6, 11, 15, 20, 32, 38, 38, 38, 38
  • 3, 11, 17, 23, 33, 38, 38, 38, 38, 38
  • 6, 14, 18, 30, 38, 38, 38, 38, 38, 38
  • 8, 12, 20, 30, 36, 38, 38, 38, 38, 38
span 1 {1 1 1}

CIF datablock 3, entity 4 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C72 H48 Cu4 Mo4 S24 (C18 H12 Cu Mo S6)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 2, 6, 10, 18, 26, 34
  • 1, 2, 4, 3, 3, 8, 14, 20, 32, 38
  • 1, 2, 4, 4, 7, 10, 18, 26, 34, 38
  • 1, 2, 4, 5, 9, 14, 20, 32, 38, 38
  • 2, 9, 13, 21, 27, 34, 38, 38, 38, 38
  • 3, 4, 3, 2, 6, 10, 18, 26, 34, 38
  • 3, 4, 3, 3, 8, 14, 20, 32, 38, 38
  • 3, 4, 4, 7, 10, 18, 26, 34, 38, 38
  • 3, 4, 5, 9, 14, 20, 32, 38, 38, 38
  • 3, 5, 9, 11, 18, 26, 34, 38, 38, 38
  • 3, 6, 11, 15, 20, 32, 38, 38, 38, 38
  • 3, 11, 17, 23, 33, 38, 38, 38, 38, 38
  • 6, 14, 18, 30, 38, 38, 38, 38, 38, 38
  • 8, 12, 20, 30, 36, 38, 38, 38, 38, 38
span 1 {1 1 1}