Structure 4330345

4330344 << 4330345 >> 4330358
Original COD entry Download CIF Download DOT

Citation: J. Palmer West; Dino Sulejmanovic; Shiou-Jyh Hwu; Jian He; Don VanDerveer; B. Keith Johnson (2012). Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units. Inorganic Chemistry, 51, pp. 9723-9729.

Formula: Bi2 Cl Cs3 Fe4 K O24 P6

Chemical name: ?

Cell parameters:

  • a = 17.167(3) Å
  • b = 17.089(3) Å
  • c = 9.928(2) Å
  • α = 90.00°
  • β = 116.66(3)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Bi8 Cl4 Fe16 O96 P24 (Bi2 Cl Fe4 O24 P6)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 18, 16, 49, 38, 98, 66, 171
  • 2, 6, 6, 19, 18, 53, 41, 107, 65, 165
  • 2, 6, 6, 19, 18, 59, 43, 98, 65, 172
  • 2, 6, 6, 21, 20, 58, 41, 97, 62, 168
  • 2, 6, 7, 21, 16, 48, 40, 105, 65, 162
  • 2, 7, 6, 18, 16, 48, 38, 100, 68, 176
  • 2, 7, 7, 19, 15, 46, 37, 100, 70, 173
  • 2, 7, 7, 22, 17, 47, 41, 115, 78, 189
  • 2, 7, 7, 22, 18, 50, 40, 106, 72, 185
  • 2, 7, 7, 22, 21, 62, 44, 111, 72, 185
  • 2, 7, 8, 24, 16, 43, 38, 113, 82, 198
  • 2, 7, 8, 25, 20, 52, 41, 119, 82, 197
  • 2, 7, 8, 25, 21, 56, 42, 115, 75, 184
  • 2, 7, 8, 25, 22, 63, 42, 103, 74, 194
  • 2, 7, 8, 26, 21, 56, 44, 123, 76, 180
  • 2, 7, 8, 26, 22, 58, 44, 115, 74, 186
  • 2, 7, 8, 26, 24, 70, 46, 110, 78, 210
  • 2, 7, 9, 29, 24, 63, 44, 119, 87, 216
  • 2, 7, 9, 30, 26, 67, 46, 124, 82, 210
  • 2, 8, 10, 26, 20, 57, 42, 120, 81, 192
  • 2, 8, 10, 27, 19, 53, 42, 123, 88, 207
  • 3, 11, 9, 24, 20, 60, 48, 127, 78, 189
  • 3, 11, 11, 27, 18, 57, 45, 125, 81, 186
  • 3, 11, 12, 32, 24, 69, 47, 128, 84, 208
  • 3, 13, 11, 27, 21, 64, 55, 145, 85, 207
  • 4, 4, 12, 11, 39, 34, 84, 49, 126, 96
  • 4, 4, 15, 13, 34, 28, 84, 60, 149, 96
  • 4, 4, 15, 14, 37, 29, 86, 63, 160, 97
  • 4, 4, 15, 15, 44, 32, 83, 61, 154, 98
  • 4, 4, 15, 16, 43, 30, 85, 59, 148, 102
  • 4, 5, 17, 12, 30, 24, 78, 61, 152, 90
  • 4, 5, 19, 19, 53, 34, 90, 66, 173, 118
  • 5, 5, 14, 12, 38, 30, 80, 56, 150, 101
  • 5, 6, 19, 14, 39, 34, 96, 70, 180, 105
  • 5, 6, 19, 15, 44, 35, 91, 59, 152, 103
  • 5, 6, 19, 16, 47, 39, 105, 68, 169, 110
  • 6, 9, 23, 15, 45, 37, 107, 74, 177, 110
span 1 {1 1 1}