Structure 4332504

4332499 << 4332504 >> 4332505
Original COD entry Download CIF Download DOT

Citation: Chandrasekaran, P.; Mague, Joel T.; Balakrishna, Maravanji S. (2006). Copper(I) Coordination Polymers [{Cu(\m-X)}2{RP(\m-NtBu)}2]n(R = OC6H4OMe-o; X = Cl, Br, and I) and Their Reversible Conversion into Mononuclear Complexes [CuX{(RP(\m-NtBu))2}2]:  Synthesis and Structural Characterization. Inorganic Chemistry, 45, pp. 6678-6683.

Formula: C26 H38 Cu2 I2 N4 O4 P2

Chemical name: catena-[(\m-diiodo(acetonitrile)dicopper(I))(\m-1,3-di-tert-butyl-2,4-bis(2-methoxyphenoxy)-[1,3,2,4]-diazadiphosphetidine)]

Cell parameters:

  • a = 13.478(1) Å
  • b = 18.104(1) Å
  • c = 15.015(10) Å
  • α = 90.00°
  • β = 108.495(1)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C48 H70 Cu4 I4 N6 O8 P4 (C24 H35 Cu2 I2 N3 O4 P2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C48 H70 Cu4 I4 N6 O8 P4 (C24 H35 Cu2 I2 N3 O4 P2)

Multiplicity: 1

span 1 {1 1 1}