Structure 4333445

4333407 << 4333445 >> 4333467
Original COD entry Download CIF Download DOT

Citation: Assoud, Abdeljalil; Xu, Jianxiao; Kleinke, Holger (2007). Structures and physical properties of new semiconducting polyselenides Ba2CudeltaAg4-deltaSe5 with unprecedented linear Se(3)4- units.. Inorganic chemistry, 46, pp. 9906-9911.

Formula: Ag2.22 Ba2 Cu1.77 Se5

Chemical name: ?

Cell parameters:

  • a = 16.0506(15) Å
  • b = 4.4308(4) Å
  • c = 9.1480(9) Å
  • α = 90.00°
  • β = 123.909(2)°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Ag4 Cu4 Se5 (Ag4 Cu4 Se5)

Multiplicity: 1

Coordination sequences:

  • 4, 22, 34, 32, 36, 76, 74, 64, 68, 128
  • 7, 22, 31, 35, 54, 55, 70, 71, 96, 91
  • 8, 21, 20, 37, 54, 59, 50, 81, 98, 97
  • 10, 20, 19, 33, 62, 54, 53, 73, 110, 88
  • 13, 19, 28, 35, 54, 55, 70, 71, 96, 91
  • 13, 20, 20, 50, 54, 48, 52, 102, 94, 80
  • 15, 18, 20, 50, 54, 48, 52, 102, 94, 80
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: Ag4 Cu4 Se5 (Ag4 Cu4 Se5)

Multiplicity: 1

Coordination sequences:

  • 4, 22, 34, 32, 36, 76, 74, 64, 68, 128
  • 7, 22, 31, 35, 54, 55, 70, 71, 96, 91
  • 8, 21, 20, 37, 54, 59, 50, 81, 98, 97
  • 10, 20, 19, 33, 62, 54, 53, 73, 110, 88
  • 13, 19, 28, 35, 54, 55, 70, 71, 96, 91
  • 13, 20, 20, 50, 54, 48, 52, 102, 94, 80
  • 15, 18, 20, 50, 54, 48, 52, 102, 94, 80
span 1 {1 1 1}