Structure 4341740

4341739 << 4341740 >> 4341741
Original COD entry Download CIF Download DOT

Citation: Gao, Jianhua; Li, Jian; Sulejmanovic, Dino; Hwu, Shiou-Jyh (2015). M3(P2O7)2(2-)-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn).. Inorganic chemistry, 54, pp. 1136-1144.

Formula: Cl Mn3 Na2 O14 P4 Rb

Chemical name: ?

Cell parameters:

  • a = 21.152(4) Å
  • b = 5.2405(10) Å
  • c = 13.853(3) Å
  • α = 90.00°
  • β = 119.45(3)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Cl4 Mn12 O56 P16 (Cl Mn3 O14 P4)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 7, 29, 27, 72, 46, 135, 98, 259
  • 2, 7, 7, 22, 20, 64, 46, 125, 81, 211
  • 2, 7, 8, 25, 23, 72, 49, 132, 86, 222
  • 2, 7, 9, 28, 24, 72, 51, 143, 92, 232
  • 2, 7, 9, 30, 24, 70, 52, 146, 97, 248
  • 2, 8, 9, 30, 25, 75, 56, 147, 94, 238
  • 2, 10, 14, 42, 30, 84, 64, 176, 104, 248
  • 3, 12, 12, 36, 27, 80, 59, 160, 99, 247
  • 4, 4, 15, 16, 52, 36, 101, 72, 196, 121
  • 4, 5, 20, 18, 54, 37, 103, 74, 208, 126
  • 5, 6, 19, 15, 48, 39, 117, 75, 187, 119
  • 6, 8, 28, 22, 62, 50, 140, 88, 216, 134
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