Structure 4342856

4342855 << 4342856 >> 4342857
Original COD entry Download CIF Download DOT

Citation: Morrison, Gregory; Ramanantoanina, Harry; Urland, Werner; Smith, Mark D.; Zur Loye, Hans-Conrad (2015). Flux Synthesis, Structure, Properties, and Theoretical Magnetic Study of Uranium(IV)-Containing A2USi6O15 (A = K, Rb) with an Intriguing Green-to-Purple, Crystal-to-Crystal Structural Transition in the K Analogue.. Inorganic chemistry, 54, pp. 5504-5511.

Formula: K2 O15 Si6 U

Cell parameters:

  • a = 7.2196(5) Å
  • b = 12.0518(8) Å
  • c = 17.1967(12) Å
  • α = 99.514(2)°
  • β = 91.002(2)°
  • γ = 106.116(2)°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O60 Si24 U4 (O15 Si6 U)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 5, 16, 15, 45, 35, 93, 57, 139
  • 2, 6, 6, 20, 14, 42, 38, 98, 56, 140
  • 2, 6, 6, 21, 16, 49, 38, 94, 64, 165
  • 2, 6, 6, 21, 18, 47, 36, 104, 61, 148
  • 2, 6, 6, 21, 18, 48, 35, 94, 58, 151
  • 2, 6, 6, 21, 18, 54, 39, 96, 62, 160
  • 2, 6, 6, 22, 17, 48, 37, 95, 63, 160
  • 2, 8, 7, 20, 18, 49, 34, 96, 60, 145
  • 2, 8, 8, 22, 18, 51, 39, 106, 66, 160
  • 2, 8, 8, 23, 18, 49, 36, 99, 64, 158
  • 2, 8, 8, 23, 19, 51, 37, 102, 63, 157
  • 4, 4, 13, 12, 35, 28, 79, 49, 122, 77
  • 4, 4, 14, 12, 37, 29, 78, 53, 135, 86
  • 4, 4, 14, 13, 37, 27, 77, 51, 129, 84
  • 4, 4, 14, 14, 40, 28, 73, 53, 143, 78
  • 6, 6, 17, 15, 40, 29, 84, 55, 133, 86
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