Structure 4344998

4344997 << 4344998 >> 4345004
Original COD entry Download CIF Download DOT

Citation: Fan, Yu-Hang; Zeng, Hui-Yi; Jiang, Xiao-Ming; Zhang, Ming-Jian; Liu, Bin-Wen; Guo, Guo-Cong; Huang, Jin-Shun (2017). Thiophosphates Containing Ag+ and Lone-Pair Cations with Interchiral Double Helix Show Both Ionic Conductivity and Phase Transition. Inorganic Chemistry, , pp. -.

Formula: Ag7 P3 Pb S12

Chemical name: ?

Cell parameters:

  • a = 10.740(3) Å
  • b = 9.899(3) Å
  • c = 21.078(5) Å
  • α = 90.00°
  • β = 118.678(11)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ag28 P12 Pb4 S48 (Ag7 P3 Pb S12)

Multiplicity: 1

Coordination sequences:

  • 2, 4, 12, 25, 54, 81, 131, 164, 226, 290
  • 2, 7, 16, 36, 59, 101, 129, 193, 238, 299
  • 3, 7, 15, 41, 61, 106, 141, 197, 252, 320
  • 3, 8, 16, 36, 60, 108, 136, 195, 238, 316
  • 3, 8, 18, 42, 60, 114, 139, 196, 254, 325
  • 3, 9, 18, 41, 59, 99, 136, 194, 246, 308
  • 3, 10, 19, 42, 72, 107, 155, 205, 256, 327
  • 3, 10, 22, 42, 66, 111, 153, 200, 261, 339
  • 3, 11, 23, 38, 71, 108, 147, 205, 244, 332
  • 4, 8, 20, 38, 76, 101, 155, 200, 262, 320
  • 4, 9, 22, 36, 71, 104, 151, 188, 268, 316
  • 4, 9, 22, 39, 79, 97, 157, 210, 263, 328
  • 4, 9, 25, 46, 73, 112, 159, 205, 271, 332
  • 4, 10, 28, 43, 78, 112, 159, 207, 271, 327
  • 4, 13, 26, 52, 73, 117, 159, 215, 272, 338
  • 4, 14, 23, 52, 76, 119, 160, 213, 268, 340
  • 4, 14, 25, 52, 77, 117, 157, 219, 267, 331
  • 4, 14, 27, 50, 77, 118, 152, 212, 274, 336
  • 5, 11, 25, 46, 82, 114, 159, 205, 272, 339
  • 5, 11, 28, 46, 77, 109, 159, 209, 273, 326
  • 5, 13, 25, 51, 75, 109, 165, 198, 270, 337
  • 5, 14, 27, 51, 80, 124, 161, 212, 276, 347
  • 5, 15, 34, 53, 85, 114, 163, 223, 277, 336
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