Structure 4350179

4350178 << 4350179 >> 4350180
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Citation: Herrera, Juan-Manuel; Pope, Simon J. A.; Adams, Harry; Faulkner, Stephen; Ward, Michael D. (2006). Structural and photophysical properties of coordination networks combining [Ru(Bpym)(CN)4]2- or [[Ru(CN)4]2(mu-bpym)]4- anions (bpym = 2,2'-bipyrimidine) with lanthanide(III) cations: sensitized near-infrared luminescence from Yb(III), Nd(III), and Er(III) following Ru-to-lanthanide energy transfer.. Inorganic chemistry, 45, pp. 3895-3904.

Formula: C16 H32 N14 O19 Ru2 Sm2

Cell parameters:

  • a = 20.268(13) Å
  • b = 6.393(4) Å
  • c = 28.096(18) Å
  • α = 90.00°
  • β = 107.944(11)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;-1;0)

Dimensionality: 1

Formula: C32 H52 N28 O32 Ru4 Sm4 (C8 H13 N7 O8 Ru Sm)

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;1;0)

Dimensionality: 1

Formula: C32 H52 N28 O32 Ru4 Sm4 (C8 H13 N7 O8 Ru Sm)

span 1 {1 1 1}