Structure 4350775

4350774 << 4350775 >> 4350776
Original COD entry Download CIF Download DOT

Citation: Bassey, Euan N.; Paddison, Joseph A. M.; Keyzer, Evan N.; Lee, Jeongjae; Manuel, Pascal; da Silva, Ivan; Dutton, Si\^an E.; Grey, Clare P.; Cliffe, Matthew J. (2020). Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2. Inorganic Chemistry, 59, pp. 11627-11639.

Formula: C2 N2 Ni S2

Chemical name: catena[bis(mu2-thiocyanato-N,S)nickel(II)]

Cell parameters:

  • a = 10.5070(5) Å
  • b = 3.61889(5) Å
  • c = 6.16252(16) Å
  • α = 90°
  • β = 107.509(3)°
  • γ = 90°

List type: noninterleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C4 N4 Ni2 S4 (C2 N2 Ni S2)

Multiplicity: 1

Coordination sequences:

  • 2, 3, 14, 16, 24, 21, 36, 32, 44, 35
  • 2, 6, 9, 20, 19, 30, 26, 40, 34, 50
  • 3, 10, 12, 20, 18, 30, 27, 40, 33, 50
  • 6, 8, 14, 14, 26, 24, 34, 28, 46, 40
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