Structure 4504858

4504857 << 4504858 >> 4504878
Original COD entry Download CIF Download DOT

Citation: Liu, Cai-Ming; Zhang, De-Qing; Zhu, Dao-Ben (2005). 3D Supramolecular Array Assembled by Cross-like Arrangement of 1D Sandwich Mixed Molybdenum−Vanadium Polyoxometalate Bridged Coordination Polymer Chains:  Hydrothermal Synthesis and Crystal Structure of {[MoVI5MoV3VIV8O40(PO4)][Ni(en)2]}[Ni(en)2]2·4H2O. Crystal Growth & Design, 5, pp. 1639-.

Formula: C12 H48 Mo8 N12 Ni3 O48 P V8

Chemical name: ?

Cell parameters:

  • a = 26.186(5) Å
  • b = 13.520(3) Å
  • c = 19.559(4) Å
  • α = 90.00°
  • β = 106.60(3)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;1;0)

Dimensionality: 1

Formula: C8 H32 Mo16 N8 Ni2 O96 P2 V16 (C4 H16 Mo8 N4 Ni O48 P V8)

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;-1;0)

Dimensionality: 1

Formula: C8 H32 Mo16 N8 Ni2 O96 P2 V16 (C4 H16 Mo8 N4 Ni O48 P V8)

span 1 {1 1 1}