Structure 4513543

4513542 << 4513543 >> 4513544

Citation: Andreychuk, Nicholas R.; Allard, Sheena R.; Parent, Shawna L. M.; Assoud, Abdeljalil; MacKinnon, Craig D. (2015). Not Too Big and Not Too Small: “Goldilocks” Anion Size for Three-Dimensional Metal--Organic Frameworks Containing Oligothiophene Dinitrile Ligands (C4H2S)n(CN)2(n= 1, 2, 3) Bridging Silver(I) Cations. Crystal Growth & Design, 15, pp. 4377-.

Formula: C29 H12 Ag F3 N4 O3.45 S7

Chemical name: ?

Cell parameters:

a = 12.7731(13) Å
b = 29.872(3) Å
c = 33.792(4) Å

α = 90.00°
β = 90.00°
γ = 90.00°

List type: interleaving

List: 3D

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C224 H96 Ag8 N32 S48 (C28 H12 Ag N4 S6)

Multiplicity: 5

Coordination sequences:

1, 2, 4, 2, 3, 6, 5, 5, 9, 11
1, 2, 4, 3, 4, 3, 5, 6, 5, 7
1, 2, 4, 3, 5, 5, 3, 2, 4, 6
2, 3, 6, 5, 5, 9, 11, 8, 9, 11
2, 4, 5, 4, 5, 5, 6, 8, 10, 7
2, 4, 5, 6, 8, 11, 9, 8, 11, 9
2, 4, 6, 6, 4, 2, 2, 6, 6, 6
3, 4, 2, 3, 6, 5, 5, 9, 11, 7
3, 4, 3, 4, 3, 5, 6, 5, 7, 10
3, 4, 3, 5, 5, 3, 2, 4, 6, 6
3, 4, 3, 5, 6, 5, 8, 12, 8, 7
3, 5, 5, 3, 3, 6, 5, 4, 7, 12
3, 5, 5, 4, 4, 3, 4, 4, 6, 9
4, 4, 4, 8, 12, 8, 8, 12, 8, 8

span 1 {1 1 1}

highlight edges

CIF datablock 1, entity 2 of 2