Structure 6000498

6000494 << 6000498 >> 6000499
Original COD entry Download CIF Download DOT

Citation: Pamela J. Hagrman; Jon Zubieta (2000). Structural influences of organonitrogen ligands on vanadium oxide solids. Hydrothermal syntheses and structures of the terpyridine vanadates [V2O4(terpy)(2)](3)[V10O28], [VO2(terpy)][V4O10], and [V9O22(terpy)(3)]. Inorganic Chemistry, 39, pp. 3252-3260.

Formula: C15 H11 N3 O12 V5

Cell parameters:

  • a = 7.77710(10) Å
  • b = 10.3595(2) Å
  • c = 25.7150(4) Å
  • α = 90.000°
  • β = 92.2860(10)°
  • γ = 90.000°

List type: interleaving

List: 2D

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Molecules

CIF datablock 4, entity 5 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: O20 V8 (O5 V2)

Multiplicity: 1

Coordination sequences:

  • 1, 4, 5, 17, 12, 29, 23, 42, 29, 56
  • 1, 4, 5, 18, 13, 30, 23, 38, 37, 54
  • 1, 5, 7, 15, 17, 28, 26, 42, 37, 50
  • 1, 5, 7, 16, 17, 28, 28, 41, 39, 52
  • 2, 8, 8, 25, 16, 33, 28, 45, 37, 60
  • 2, 9, 10, 23, 18, 35, 30, 40, 48, 57
  • 3, 10, 7, 24, 17, 36, 29, 49, 34, 55
  • 3, 10, 7, 26, 19, 31, 32, 48, 40, 60
  • 3, 11, 9, 23, 19, 33, 25, 48, 39, 60
  • 3, 12, 11, 20, 23, 37, 29, 49, 42, 54
  • 5, 5, 17, 12, 29, 23, 42, 29, 56, 40
  • 5, 5, 18, 13, 30, 23, 38, 37, 54, 46
  • 6, 7, 15, 17, 28, 26, 42, 37, 50, 48
  • 6, 7, 16, 17, 28, 28, 41, 39, 52, 46
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CIF datablock 5, entity 6 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: O20 V8 (O5 V2)

Multiplicity: 1

Coordination sequences:

  • 1, 4, 5, 17, 12, 29, 23, 42, 29, 56
  • 1, 4, 5, 18, 13, 30, 23, 38, 37, 54
  • 1, 5, 7, 15, 17, 28, 26, 42, 37, 50
  • 1, 5, 7, 16, 17, 28, 28, 41, 39, 52
  • 2, 8, 8, 25, 16, 33, 28, 45, 37, 60
  • 2, 9, 10, 23, 18, 35, 30, 40, 48, 57
  • 3, 10, 7, 24, 17, 36, 29, 49, 34, 55
  • 3, 10, 7, 26, 19, 31, 32, 48, 40, 60
  • 3, 11, 9, 23, 19, 33, 25, 48, 39, 60
  • 3, 12, 11, 20, 23, 37, 29, 49, 42, 54
  • 5, 5, 17, 12, 29, 23, 42, 29, 56, 40
  • 5, 5, 18, 13, 30, 23, 38, 37, 54, 46
  • 6, 7, 15, 17, 28, 26, 42, 37, 50, 48
  • 6, 7, 16, 17, 28, 28, 41, 39, 52, 46
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