Structure 7000746

7000735 << 7000746 >> 7000755
Original COD entry Download CIF Download DOT

Citation: Ganesamoorthy, Chelladurai; Balakrishna, Maravanji S.; Mague, Joel T. (2009). Di-, tetra- and polynuclear RhI complexes containing phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions. Dalton Transactions, , pp. 1984-1990.

Formula: C66 H64 Cl2 N4 O16 P4 Rh2

Chemical name: catena-Poly{dichloro(\m-1,4-bis(bis(bis(2-methoxyphenoxy)phospino)amino)benzene-1\k^2^P,P':2\k^2^P",P"')(\m-pyrazine-1\kN:2\kN')dirhodium(I)}

Cell parameters:

  • a = 16.9519(9) Å
  • b = 11.3413(6) Å
  • c = 18.325(1) Å
  • α = 90.00°
  • β = 110.072(1)°
  • γ = 90.00°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C68 H70 Cl2 N4 O18 P4 Rh2 (C34 H35 Cl N2 O9 P2 Rh)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0)

Dimensionality: 1

Formula: C68 H70 Cl2 N4 O18 P4 Rh2 (C34 H35 Cl N2 O9 P2 Rh)

Multiplicity: 1

span 1 {1 1 1}