Structure 7005108

7005107 << 7005108 >> 7005153
Original COD entry Download CIF Download DOT

Citation: Mishra, Shashank; Pfalzgraf, Liliane G Hubert; Jeanneau, Erwann; Chermette, Henry (2007). From discrete [Y(DMF)8][Cu4(mu3-I)2(mu-I)3I2] ion pairs to extended [Y(DMF)6(H2O)2][Cu7(mu4-I)3(mu3-I)2(mu-I)4(I)]1infinity and [Y(DMF)6(H2O)3][Cu(I)7Cu(II)2(mu3-I)8(mu-I)6]2infinity arrays by H-bond templating in a confined solvent-free environment.. Dalton transactions (Cambridge, England : 2003), , pp. 410-413.

Formula: C18 H42 Cu9 I14 N6 O9 Y

Cell parameters:

  • a = 13.7471(14) Å
  • b = 13.7471(14) Å
  • c = 60.040(5) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 6, entity 7 of 6

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu9 I14 (Cu9 I14)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 11, 14, 18, 22, 28, 36, 36
  • 3, 9, 9, 12, 15, 18, 24, 30, 36, 33
  • 3, 10, 9, 12, 15, 19, 24, 30, 37, 36
  • 6, 8, 10, 12, 16, 20, 24, 32, 38, 36
  • 7, 8, 10, 13, 16, 20, 26, 32, 37, 34
span 1 {1 1 1}

CIF datablock 7, entity 8 of 6

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu9 I14 (Cu9 I14)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 11, 14, 18, 22, 28, 36, 36
  • 3, 9, 9, 12, 15, 18, 24, 30, 36, 33
  • 3, 10, 9, 12, 15, 19, 24, 30, 37, 36
  • 6, 8, 10, 12, 16, 20, 24, 32, 38, 36
  • 7, 8, 10, 13, 16, 20, 26, 32, 37, 34
span 1 {1 1 1}

CIF datablock 8, entity 9 of 6

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu9 I14 (Cu9 I14)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 11, 14, 18, 22, 28, 36, 36
  • 3, 9, 9, 12, 15, 18, 24, 30, 36, 33
  • 3, 10, 9, 12, 15, 19, 24, 30, 37, 36
  • 6, 8, 10, 12, 16, 20, 24, 32, 38, 36
  • 7, 8, 10, 13, 16, 20, 26, 32, 37, 34
span 1 {1 1 1}

CIF datablock 9, entity 10 of 6

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu9 I14 (Cu9 I14)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 11, 14, 18, 22, 28, 36, 36
  • 3, 9, 9, 12, 15, 18, 24, 30, 36, 33
  • 3, 10, 9, 12, 15, 19, 24, 30, 37, 36
  • 6, 8, 10, 12, 16, 20, 24, 32, 38, 36
  • 7, 8, 10, 13, 16, 20, 26, 32, 37, 34
span 1 {1 1 1}

CIF datablock 10, entity 11 of 6

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu9 I14 (Cu9 I14)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 11, 14, 18, 22, 28, 36, 36
  • 3, 9, 9, 12, 15, 18, 24, 30, 36, 33
  • 3, 10, 9, 12, 15, 19, 24, 30, 37, 36
  • 6, 8, 10, 12, 16, 20, 24, 32, 38, 36
  • 7, 8, 10, 13, 16, 20, 26, 32, 37, 34
span 1 {1 1 1}

CIF datablock 11, entity 12 of 6

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cu9 I14 (Cu9 I14)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 9, 11, 14, 18, 22, 28, 36, 36
  • 3, 9, 9, 12, 15, 18, 24, 30, 36, 33
  • 3, 10, 9, 12, 15, 19, 24, 30, 37, 36
  • 6, 8, 10, 12, 16, 20, 24, 32, 38, 36
  • 7, 8, 10, 13, 16, 20, 26, 32, 37, 34
span 1 {1 1 1}