Structure 7011728

7011714 << 7011728 >> 7011808
Original COD entry Download CIF Download DOT

Citation: Uehara, Kazuhiro; Hikichi, Shiro; Akita, Munetaka (2002). Highly labile cationic tris-acetonitrile complexes, [TpRM(NCMe)3]OTf (M = Ni, Co; TpR: hydrotrispyrazolylborato, R = Ph, Me and iPr2): versatile precursors for TpR-containing nickel and cobalt complexes. Journal of the Chemical Society, Dalton Transactions, , pp. 3529-.

Formula: C47.5 H51 B Cl5 F3 N8 Ni O3 S

Cell parameters:

  • a = 20.076(1) Å
  • b = 16.732(1) Å
  • c = 29.573(2) Å
  • α = 90°
  • β = 102.519(3)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C76 H64 B2 N16 Ni2 (C38 H32 B N8 Ni)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C76 H64 B2 N16 Ni2 (C38 H32 B N8 Ni)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 2, entity 3 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C76 H64 B2 N16 Ni2 (C38 H32 B N8 Ni)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 3, entity 4 of 4

Basis: (0;1;0)

Dimensionality: 1

Formula: C76 H64 B2 N16 Ni2 (C38 H32 B N8 Ni)

Multiplicity: 1

span 1 {1 1 1}