Structure 7012628

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Citation: Rarig, Jr., Randy S.; Zubieta, Jon (2003). Solid state coordination chemistry: secondary metal--ligand influences on the structures of vanadium oxides. Hydrothermal syntheses and structures of [Zn(tpytrz)2V2O6], [Zn3(tpytrz)2(H2O)2V6O18]·6H2O and [Cu3(tpytrz)2(H2O)2V8O23]·3H2O (tpytrz = 2,4,6-tri(4-pyridyl)-1,3,5-triazine)Electronic supplementary information (ESI) available: colour versions of Fig. 1--3. See http://www.rsc.org/suppdata/dt/b2/b212458k/. Dalton Transactions, , pp. 1861-.

Formula: C18 H20 N6 O13 V3 Zn1.5

Chemical name: ?

Cell parameters:

  • a = 7.8393(3) Å
  • b = 22.8107(9) Å
  • c = 15.1124(6) Å
  • α = 90.00°
  • β = 102.3630(10)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

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Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C72 H48 N24 O40 V12 Zn6 (C36 H24 N12 O20 V6 Zn3)

Multiplicity: 1

span 1 {1 1 1}