Structure 7030803

7030802 << 7030803 >> 7030804
Original COD entry Download CIF Download DOT

Citation: Bhardwaj, Neha; Gupta, Akanksha; Uma, S. (2014). Evidence of cationic mixing and ordering in the honeycomb layer of Li4MSbO6 (M(iii) = Cr, Mn, Al, Ga) (S.G. C2/c) oxides.. Dalton transactions (Cambridge, England : 2003), 43, pp. 12050-12057.

Formula: Li1.995 Mn0.54 O3 Sb0.465

Chemical name: ?

Cell parameters:

  • a = 5.09652(6) Å
  • b = 8.82700(20) Å
  • c = 9.85425(17) Å
  • α = 90.0°
  • β = 99.9119(7)°
  • γ = 90.0°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Li6 Mn4 O12 Sb4 (Li3 Mn2 O6 Sb2)

Multiplicity: 1

Coordination sequences:

  • 1, 12, 42, 64, 90, 120, 142, 168, 198, 220
  • 1, 15, 36, 67, 93, 114, 145, 171, 192, 223
  • 2, 12, 40, 65, 91, 118, 143, 169, 196, 221
  • 3, 21, 47, 73, 102, 125, 151, 180, 203, 229
  • 4, 24, 55, 78, 102, 133, 156, 180, 211, 234
  • 4, 26, 51, 80, 104, 129, 158, 182, 207, 236
  • 13, 37, 64, 92, 118, 142, 170, 196, 220, 248
  • 13, 42, 64, 90, 120, 142, 168, 198, 220, 246
  • 14, 40, 65, 91, 118, 143, 169, 196, 221, 247
  • 16, 36, 67, 93, 114, 145, 171, 192, 223, 249
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Li6 Mn4 O12 Sb4 (Li3 Mn2 O6 Sb2)

Multiplicity: 1

Coordination sequences:

  • 1, 12, 42, 64, 90, 120, 142, 168, 198, 220
  • 1, 15, 36, 67, 93, 114, 145, 171, 192, 223
  • 2, 12, 40, 65, 91, 118, 143, 169, 196, 221
  • 3, 21, 47, 73, 102, 125, 151, 180, 203, 229
  • 4, 24, 55, 78, 102, 133, 156, 180, 211, 234
  • 4, 26, 51, 80, 104, 129, 158, 182, 207, 236
  • 13, 37, 64, 92, 118, 142, 170, 196, 220, 248
  • 13, 42, 64, 90, 120, 142, 168, 198, 220, 246
  • 14, 40, 65, 91, 118, 143, 169, 196, 221, 247
  • 16, 36, 67, 93, 114, 145, 171, 192, 223, 249
span 1 {1 1 1}