Structure 7037018

7037017 << 7037018 >> 7037019
Original COD entry Download CIF Download DOT

Citation: Lin, Xinsong; Tabassum, Danisa; Mar, Arthur (2015). Narrowing the gap: from semiconductor to semimetal in the homologous series of rare-earth zinc arsenides RE2-yZn4As4·n(REAs) and Mn-substituted derivatives RE2-yMnxZn4-xAs4·n(REAs) (RE = La-Nd, Sm, Gd).. Dalton transactions (Cambridge, England : 2003), 44, pp. 20254-20264.

Formula: As8 Nd5.43 Zn4

Chemical name: neodymium zinc arsenide (5.4/4/8)

Cell parameters:

  • a = 4.2038(11) Å
  • b = 4.2038(11) Å
  • c = 82.97(2) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: As24 Nd18 Zn18 (As4 Nd3 Zn3)

Multiplicity: 1

Coordination sequences:

  • 6, 18, 38, 66, 102, 188, 332, 574, 698, 702
  • 6, 18, 38, 66, 117, 197, 355, 502, 650, 769
  • 6, 18, 38, 76, 139, 248, 331, 414, 569, 810
  • 6, 18, 44, 91, 179, 254, 303, 381, 536, 712
  • 6, 21, 53, 120, 186, 236, 306, 402, 491, 646
  • 7, 25, 71, 127, 177, 239, 321, 405, 497, 609
  • 7, 28, 77, 124, 174, 241, 319, 402, 499, 607
  • 8, 41, 75, 123, 182, 246, 324, 413, 507, 615
  • 11, 43, 79, 124, 183, 247, 325, 414, 508, 616
  • 11, 46, 82, 130, 190, 255, 334, 424, 519, 628
  • 18, 42, 86, 132, 186, 260, 336, 420, 524, 630
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