Structure 7038809

7038805 << 7038809 >> 7038831
Original COD entry Download CIF Download DOT

Citation: Lasanta, Tania; L\'opez-de-Luzuriaga, Jos\'e M; Monge, Miguel; Olmos, M. Elena; Pascual, David (2016). Synthesis of the molecular amalgam [{AuHg2(o-C6F4)3}{Hg3(o-C6F4)3}](-): a rare example of a heterometallic homoleptic metallacycle.. Dalton transactions (Cambridge, England : 2003), 45, pp. 6334-6338.

Formula: C42 H18 Au2 F24 Hg5 P2

Chemical name: ?

Cell parameters:

  • a = 22.8022(12) Å
  • b = 16.7195(9) Å
  • c = 13.2363(4) Å
  • α = 90°
  • β = 108.232(3)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C72 Au4 F48 Hg12 (C18 Au F12 Hg3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 4, 11, 22, 34, 45, 50
  • 1, 2, 4, 3, 5, 12, 21, 33, 45, 50
  • 1, 2, 4, 3, 5, 12, 23, 38, 49, 50
  • 1, 2, 4, 3, 6, 13, 22, 37, 49, 50
  • 1, 2, 4, 4, 6, 14, 25, 38, 48, 48
  • 1, 2, 4, 6, 12, 22, 34, 45, 50, 51
  • 1, 2, 4, 7, 13, 21, 33, 45, 50, 51
  • 1, 2, 4, 7, 13, 23, 38, 49, 50, 48
  • 1, 2, 4, 8, 14, 22, 37, 49, 50, 48
  • 1, 2, 5, 8, 15, 25, 38, 48, 48, 45
  • 3, 4, 3, 4, 11, 22, 34, 45, 50, 51
  • 3, 4, 3, 5, 12, 21, 33, 45, 50, 51
  • 3, 4, 3, 5, 12, 23, 38, 49, 50, 48
  • 3, 4, 3, 6, 13, 22, 37, 49, 50, 48
  • 3, 4, 4, 6, 14, 25, 38, 48, 48, 45
  • 3, 4, 6, 12, 22, 34, 45, 50, 51, 51
  • 3, 4, 7, 13, 21, 33, 45, 50, 51, 51
  • 3, 4, 7, 13, 23, 38, 49, 50, 48, 46
  • 3, 4, 8, 14, 22, 37, 49, 50, 48, 46
  • 3, 5, 8, 15, 25, 38, 48, 48, 45, 45
  • 3, 7, 14, 23, 34, 45, 50, 51, 51, 48
  • 3, 8, 15, 22, 33, 45, 50, 51, 51, 48
  • 3, 8, 15, 24, 38, 49, 50, 48, 46, 44
  • 3, 9, 16, 23, 37, 49, 50, 48, 46, 44
  • 4, 9, 17, 26, 38, 48, 48, 45, 45, 46
  • 4, 12, 25, 39, 49, 53, 51, 47, 46, 45
  • 5, 13, 25, 37, 46, 50, 51, 51, 48, 45
  • 6, 14, 26, 41, 50, 50, 48, 46, 44, 46
  • 6, 17, 29, 41, 49, 48, 45, 45, 46, 45
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C72 Au4 F48 Hg12 (C18 Au F12 Hg3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 4, 11, 22, 34, 45, 50
  • 1, 2, 4, 3, 5, 12, 21, 33, 45, 50
  • 1, 2, 4, 3, 5, 12, 23, 38, 49, 50
  • 1, 2, 4, 3, 6, 13, 22, 37, 49, 50
  • 1, 2, 4, 4, 6, 14, 25, 38, 48, 48
  • 1, 2, 4, 6, 12, 22, 34, 45, 50, 51
  • 1, 2, 4, 7, 13, 21, 33, 45, 50, 51
  • 1, 2, 4, 7, 13, 23, 38, 49, 50, 48
  • 1, 2, 4, 8, 14, 22, 37, 49, 50, 48
  • 1, 2, 5, 8, 15, 25, 38, 48, 48, 45
  • 3, 4, 3, 4, 11, 22, 34, 45, 50, 51
  • 3, 4, 3, 5, 12, 21, 33, 45, 50, 51
  • 3, 4, 3, 5, 12, 23, 38, 49, 50, 48
  • 3, 4, 3, 6, 13, 22, 37, 49, 50, 48
  • 3, 4, 4, 6, 14, 25, 38, 48, 48, 45
  • 3, 4, 6, 12, 22, 34, 45, 50, 51, 51
  • 3, 4, 7, 13, 21, 33, 45, 50, 51, 51
  • 3, 4, 7, 13, 23, 38, 49, 50, 48, 46
  • 3, 4, 8, 14, 22, 37, 49, 50, 48, 46
  • 3, 5, 8, 15, 25, 38, 48, 48, 45, 45
  • 3, 7, 14, 23, 34, 45, 50, 51, 51, 48
  • 3, 8, 15, 22, 33, 45, 50, 51, 51, 48
  • 3, 8, 15, 24, 38, 49, 50, 48, 46, 44
  • 3, 9, 16, 23, 37, 49, 50, 48, 46, 44
  • 4, 9, 17, 26, 38, 48, 48, 45, 45, 46
  • 4, 12, 25, 39, 49, 53, 51, 47, 46, 45
  • 5, 13, 25, 37, 46, 50, 51, 51, 48, 45
  • 6, 14, 26, 41, 50, 50, 48, 46, 44, 46
  • 6, 17, 29, 41, 49, 48, 45, 45, 46, 45
span 1 {1 1 1}