Structure 7062547

7062538 << 7062547 >> 7062548
Original COD entry Download CIF Download DOT

Citation: Shvanskaya, Larisa; Krikunova, Polina; Nikolaeva, Irina; Lyssenko, Konstantin; Pokryshkin, Nikolay; Timoshenko, Victor (2023). Novel bismuth oxosalts, \b-Bi3O3(VO4) and KBi5O5(PO4)2: synthesis and effect of hydrothermal pressure on the crystal structure. New Journal of Chemistry, 47, pp. 13911-13917.

Formula: Bi2.5 K0.5 O6.5 P

Chemical name: potassium pentabismuth pentaoxo-diphosphate

Cell parameters:

  • a = 8.0264(6) Å
  • b = 5.4616(4) Å
  • c = 27.769(2) Å
  • α = 90°
  • β = 95.697(2)°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Bi20 O52 P8 (Bi5 O13 P2)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 3, 11, 11, 30, 26, 69, 66, 129
  • 2, 6, 6, 18, 20, 50, 36, 92, 91, 186
  • 2, 7, 6, 18, 17, 48, 47, 94, 73, 161
  • 2, 7, 6, 18, 17, 48, 47, 94, 74, 165
  • 2, 7, 7, 25, 27, 61, 49, 102, 74, 187
  • 2, 7, 7, 25, 29, 63, 49, 102, 73, 189
  • 2, 7, 8, 21, 17, 48, 45, 90, 66, 161
  • 2, 8, 12, 32, 32, 71, 49, 123, 93, 202
  • 2, 8, 12, 32, 34, 74, 49, 126, 94, 203
  • 3, 7, 9, 26, 25, 59, 40, 109, 92, 188
  • 3, 7, 9, 26, 26, 61, 39, 108, 94, 191
  • 4, 3, 11, 11, 30, 26, 69, 66, 129, 98
  • 4, 4, 18, 25, 55, 39, 87, 64, 167, 125
  • 4, 5, 13, 15, 42, 30, 69, 61, 153, 123
  • 4, 6, 16, 19, 44, 35, 99, 79, 158, 99
  • 4, 7, 18, 19, 45, 35, 99, 77, 152, 102
  • 4, 12, 14, 31, 28, 80, 68, 142, 87, 199
  • 4, 12, 14, 31, 29, 83, 69, 143, 86, 197
  • 5, 5, 15, 12, 38, 41, 78, 58, 131, 94
  • 6, 10, 22, 21, 58, 48, 112, 81, 173, 107
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