Structure 7062548

7062547 << 7062548 >> 7062590
Original COD entry Download CIF Download DOT

Citation: Shvanskaya, Larisa; Krikunova, Polina; Nikolaeva, Irina; Lyssenko, Konstantin; Pokryshkin, Nikolay; Timoshenko, Victor (2023). Novel bismuth oxosalts, \b-Bi3O3(VO4) and KBi5O5(PO4)2: synthesis and effect of hydrothermal pressure on the crystal structure. New Journal of Chemistry, 47, pp. 13911-13917.

Formula: Bi0.75 O1.75 V0.25

Chemical name: tribismuth oxovanadate

Cell parameters:

  • a = 5.7337(6) Å
  • b = 7.1029(8) Å
  • c = 9.2980(10) Å
  • α = 80.334(3)°
  • β = 78.576(3)°
  • γ = 68.557(3)°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Bi6 O14 V2 (Bi3 O7 V)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 7, 21, 24, 55, 50, 120, 87, 177
  • 2, 7, 7, 19, 20, 48, 50, 113, 93, 196
  • 2, 7, 8, 20, 22, 55, 57, 128, 98, 205
  • 2, 7, 8, 21, 22, 51, 55, 125, 97, 207
  • 3, 8, 10, 27, 27, 62, 50, 120, 96, 203
  • 3, 8, 11, 29, 28, 70, 53, 119, 93, 195
  • 3, 9, 10, 25, 27, 69, 54, 122, 96, 202
  • 4, 4, 14, 15, 34, 37, 93, 81, 167, 115
  • 4, 6, 16, 18, 47, 37, 88, 74, 161, 118
  • 4, 6, 16, 18, 48, 41, 96, 71, 155, 122
  • 5, 6, 15, 15, 41, 42, 92, 78, 177, 119
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