Structure 7104060

7104059 << 7104060 >> 7104064
Original COD entry Download CIF Download DOT

Citation: Rather, Beth; Zaworotko, Michael J (2003). A 3D metal-organic network, [Cu2(glutarate)2(4,4'-bipyridine)], that exhibits single-crystal to single-crystal dehydration and rehydration.. Chemical communications (Cambridge, England), , pp. 830-831.

Formula: C22 H24 Cu2 N2 O13

Chemical name: ?

Cell parameters:

  • a = 23.911(3) Å
  • b = 11.8685(15) Å
  • c = 9.2063(12) Å
  • α = 90.00°
  • β = 90.350(2)°
  • γ = 90.00°

List type: interleaving

List: 1-3D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 3

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C88 H96 Cu8 N8 O32 (C11 H12 Cu N O4)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 3

Basis: (0;0;1)

Dimensionality: 1

Formula: O32 (O)

Multiplicity: 1

Coordination sequences:

  • 2, 4, 12, 11, 4, 4, 10, 6, 8, 4
  • 2, 8, 8, 9, 6, 4, 10, 6, 8, 4
  • 3, 3, 5, 9, 7, 7, 9, 6, 7, 5
  • 3, 7, 8, 8, 7, 7, 5, 9, 5, 6
  • 4, 5, 6, 8, 5, 9, 6, 6, 7, 5
  • 4, 9, 5, 5, 11, 7, 6, 4, 7, 8
  • 5, 5, 6, 8, 6, 10, 7, 4, 7, 8
  • 5, 5, 9, 7, 6, 8, 5, 9, 5, 6
  • 7, 7, 5, 7, 8, 7, 6, 4, 7, 8
span 1 {1 1 1}

CIF datablock 2, entity 3 of 3

Basis: (0;0;1)

Dimensionality: 1

Formula: O32 (O)

Multiplicity: 1

Coordination sequences:

  • 2, 4, 12, 11, 4, 4, 10, 6, 8, 4
  • 2, 8, 8, 9, 6, 4, 10, 6, 8, 4
  • 3, 3, 5, 9, 7, 7, 9, 6, 7, 5
  • 3, 7, 8, 8, 7, 7, 5, 9, 5, 6
  • 4, 5, 6, 8, 5, 9, 6, 6, 7, 5
  • 4, 9, 5, 5, 11, 7, 6, 4, 7, 8
  • 5, 5, 6, 8, 6, 10, 7, 4, 7, 8
  • 5, 5, 9, 7, 6, 8, 5, 9, 5, 6
  • 7, 7, 5, 7, 8, 7, 6, 4, 7, 8
span 1 {1 1 1}