Structure 7104623

7104614 << 7104623 >> 7104637
Original COD entry Download CIF Download DOT

Citation: Guo, Sheng-Ping; Guo, Guo-Cong; Wang, Ming-Sheng; Zou, Jian-Ping; Zeng, Hui-Yi; Cai, Li-Zhen; Huang, Jin-Shun (2009). A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate.. Chemical communications (Cambridge, England), 34, pp. 4366-4368.

Formula: B12 Ga3 I K3 S12 Sm

Chemical name: K3ISmGa3B12S12

Cell parameters:

  • a = 12.9213(16) Å
  • b = 12.9213(16) Å
  • c = 9.3181(17) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 120.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: B24 Ga6 S24 Sm2 (B12 Ga3 S12 Sm)

Multiplicity: 1

Coordination sequences:

  • 2, 8, 13, 24, 32, 50, 69, 100, 118, 158
  • 3, 13, 18, 37, 37, 67, 74, 135, 131, 228
  • 4, 6, 22, 32, 46, 48, 90, 112, 156, 166
  • 6, 11, 13, 18, 33, 67, 70, 87, 108, 176
  • 6, 12, 14, 19, 40, 55, 86, 85, 130, 173
  • 6, 12, 30, 30, 60, 62, 108, 114, 204, 186
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