Structure 7108388

7108380 << 7108388 >> 7108409
Original COD entry Download CIF Download DOT

Citation: Monica Lanchas; Daniel Vallejo-Sanchez; Garikoitz Beobide; Oscar Castillo; Andres T. Aguayo; Antonio Luque; Pascual Roman (2012). A direct reaction approach for the synthesis of zeolitic imidazolate frameworks: template and temperature mediated control on network topology and crystal size. Chem.Commun., 48, pp. 9930-.

Formula: C36 H53 Co5 N21 O8

Chemical name: poly-[[dekakis(mu-imidazolato-KN:KN')pentacobalt(II)]-water-4-methylpyridine(1/8/1)

Cell parameters:

  • a = 24.3302(11) Å
  • b = 9.5623(5) Å
  • c = 24.6111(16) Å
  • α = 90.00°
  • β = 91.542(5)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

span 1 {1 1 1}
Ctrl-click to select multiple nodes

JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C120 H120 Co20 N80 (C6 H6 Co N4)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 5, 9, 18, 18, 15, 27, 51
  • 1, 2, 4, 5, 9, 18, 18, 15, 27, 54
  • 1, 2, 4, 8, 12, 24, 12, 18, 35, 67
  • 1, 2, 4, 8, 12, 24, 12, 18, 36, 72
  • 3, 4, 5, 9, 18, 18, 15, 27, 51, 49
  • 3, 4, 5, 9, 18, 18, 15, 27, 54, 53
  • 3, 4, 5, 9, 18, 18, 15, 27, 54, 54
  • 3, 4, 8, 12, 24, 12, 18, 35, 67, 30
  • 3, 4, 8, 12, 24, 12, 18, 35, 67, 31
  • 3, 4, 8, 12, 24, 12, 18, 36, 72, 33
  • 3, 4, 8, 12, 24, 12, 18, 36, 72, 34
  • 3, 4, 8, 12, 24, 12, 18, 36, 72, 35
  • 3, 7, 8, 15, 12, 21, 24, 44, 33, 54
  • 3, 7, 8, 15, 12, 21, 24, 44, 33, 55
  • 3, 7, 8, 15, 12, 21, 24, 45, 35, 57
  • 3, 7, 8, 15, 12, 21, 24, 45, 35, 58
  • 3, 7, 8, 15, 12, 21, 24, 45, 36, 61
  • 3, 7, 8, 15, 12, 21, 24, 45, 36, 62
  • 4, 8, 16, 8, 12, 24, 48, 23, 32, 61
  • 4, 8, 16, 8, 12, 24, 48, 24, 36, 68
  • 4, 8, 16, 8, 12, 24, 48, 24, 36, 69
  • 4, 8, 16, 8, 12, 24, 48, 24, 36, 70
span 1 {1 1 1}