Structure 7114222

7114211 << 7114222 >> 7114227

Citation: Cave, Dale; Gascon, Jos\'e-Miguel; Bond, Andrew D.; Teat, Simon J.; Wood, Paul T. (2002). Layered metal organosulfides: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4). Chemical Communications, , pp. 1050-.

Formula: C7 H4 Co O2 S

Cell parameters:

a = 27.890(2) Å
b = 7.6926(6) Å
c = 6.7497(5) Å

α = 90.00°
β = 103.895(2)°
γ = 90.00°

List type: interleaving

List: 2D

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: C28 H16 Co4 O8 S4 (C7 H4 Co O2 S)

Multiplicity: 1

Coordination sequences:

1, 2, 4, 3, 3, 4, 13, 18, 35, 45
1, 2, 4, 3, 3, 9, 11, 25, 32, 56
1, 2, 4, 5, 5, 13, 18, 35, 45, 73
1, 2, 4, 5, 10, 11, 25, 32, 56, 60
2, 6, 10, 22, 28, 47, 51, 74, 71, 98
3, 4, 3, 3, 4, 13, 18, 35, 45, 73
3, 4, 3, 3, 9, 11, 25, 32, 56, 60
3, 4, 5, 5, 13, 18, 35, 45, 73, 72
3, 4, 5, 10, 11, 25, 32, 56, 60, 85
3, 5, 13, 17, 32, 40, 64, 62, 85, 85
3, 6, 7, 14, 18, 35, 45, 73, 72, 94
3, 6, 12, 12, 25, 32, 56, 60, 85, 82
3, 9, 12, 26, 36, 54, 51, 76, 82, 106
3, 10, 14, 26, 31, 54, 57, 78, 75, 101
5, 8, 18, 24, 44, 46, 65, 66, 92, 88

span 1 {1 1 1}

highlight edges

CIF datablock 1, entity 2 of 2